30results about How to "Achieve large area growth" patented technology

The invention relates to a process for preparing a stretchable supercapacitor based on a highly conductive graphene/nickel particle mixed structure. Firstly, a chemical vapor deposition method is used for preparing spongy graphene material on a nickel foam, and the prepared graphene/nickel foam are immersed in an etching solution for slow reaction so that most of the nickel metal can be chemically displaced into various small nickel particles; secondly, the spongy graphene/nickel particle mixed structure is fished out from the etching solution by using a seal-type fishing method, cleaned and dried, and a pre-stretched elastic substrate slowly returns back to the original length or area; and thirdly, the prepared stretchable graphene/nickel particle mixed structure is used as electrode material, and an all-solid-state stretchable supercapacitor is prepared according to the elastomer/electrode/solid electrolyte/electrode/elastomer structure. According to the invention, the capacitance of a conventional capacitor is increased, contact resistance is reduced, the stretching stability, frequency and performance are excellent, the cost is low, and the method is controllable and suitable for mass production.

The invention discloses a carbon nano tube/porous ceramic hollow fiber composite ultrafiltration membrane as well as a preparation method and application thereof. The preparation method comprises the following steps: carrying out ultrasonic vibration on a hollow fiber ceramic membrane used as a carrier with absolute ethyl alcohol and washing the hollow fiber ceramic membrane with de-ionized water until the hollow fiber ceramic membrane is neutral; drying to obtain the treated carrier; coating a Ni(NO3)2 solution onto the treated carrier by using an impregnation coating method; after drying, putting the carrier into a muffle furnace to be roasted to obtain a hollow fiber membrane loaded with a nickel oxide catalyst; putting the hollow fiber membrane into a quartz reaction tube and introducing N2 and H2 into the quartz reaction tube to reduce a catalyst; and switching into hydrogen gas and raising the temperature, switching a gas flow into pure methane gas and carrying out a high-temperature reaction to obtain the product. The carbon nano tube/porous ceramic hollow fiber composite ultrafiltration membrane can be used for separating liquid-water emulsion liquid and bacteria, and has a very good effect of removing PM1 fine particles in atmosphere.

The invention discloses a molybdenum disulfide/gold nanoparticle mixed structure biosensor material and a preparation method thereof. The molybdenum disulfide/gold nanoparticle mixed structure biosensor material comprises a glass fiber paper substrate, two-dimensional molybdenum disulfide adhered to the glass fiber paper substrate and gold nanoparticles adhered to the two-dimensional molybdenum disulfide. Molybdenum disulfide growth temperature is accurately controlled. Grown molybdenum disulfide has low defect peak and high crystalline quality. Grown molybdenum disulfide size is only limited by CVD cavity, and large-area growth of molybdenum disulfide can be realized. The molybdenum disulfide/metal particle mixed structure with grown metal particles has extremely high chemisorption and physical strengthening mechanisms. By the etching method for growth of gold particles, etching time can be controlled to accurately control size of the gold particles. In addition, the gold particles can uniformly grow on the whole material, which is beneficial to detection of biomolecules. The prepared biosensor can simultaneously realize separation and detection of biomolecules. The method is simple and controllable, is low-cost, and has high application value.

The invention relates to a method for preparing ternary-component AlxGaI-xN nanocone, realizing control in the full-ingredient range (x is larger than 0 and smaller than 1). The method for preparing the ternary-component AlxGaI-xN nanocone comprises the following steps of: making anhydrous GaCl3 as a gallium source and anhydrous AlCl3 as an aluminum source with a nitrogen source by adopting a chemical vapor deposition method under the condition that the evaporation temperatures of GaCl3 and AlCl3 are respectively 70-90 DEG C and 130-150 DEG C to generate single-phase AlxGaI-xN nanocone, wherein x is larger than 0 and smaller than 1, the preferred nitrogen source is NH3, and the deposition temperature is 650-800 DEG C. In the invention, the vapor partial pressure of reaction precursors GaCl3 and AlCl3 is finely controlled in a tube furnace of a three-segment temperature area to obtain a one-dimensional nano material with a single-crystal structure and uniformly distributed components, and the atom ratio of Al/Ga can be controlled in the full-ingredient range (x is larger than 0 and smaller than 1) by changing growth conditions.

The invention discloses a bent optical fiber ATR (attenuated total reflectance) glucose sensor reinforced on the basis of silver nanoparticles. The bent optical fiber ATR glucose sensor comprises an optical fiber. The optical fiber comprises an optical fiber core and optical fiber cladding, the optical fiber cladding wraps the outer periphery of the optical fiber core, optical fiber connectors which are used for being connected with external components are respectively connected to two ends of the optical fiber, a bent sensitive area is formed in the middle of the optical fiber, and the silver nanoparticles grow on the outer surface of the portion, which is positioned in the sensitive area, of the optical fiber. The optical fiber is a multi-mode optical fiber. The optical fiber core and the optical fiber cladding are made of silver halide materials, and light with the wavelength ranging from 4 micrometers to 18 micrometers can be transmitted through the optical fiber core and the optical fiber cladding. The portion, which is positioned in the sensitive area, of the optical fiber is of a U-shaped structure or a single-ring structure or a structure with two or more rings. The diameter of each silver nanoparticle ranges from 20 nanometers to 100 nanometers. The bent optical fiber ATR glucose sensor has the advantages that the bent optical fiber ATR glucose sensor is simple in structure and operation, small in size, easy to process and low in cost, and can be subcutaneously implanted into a human body, so that the blood glucose concentration of the human body can be continuously monitored in an online manner and can be directly measured in vivo, and the requirement on continuously monitoring the blood glucose concentration of the human body in real time can be met.

The invention discloses a method of growing a graphene film on an insulating substrate in the absence of a catalyst. The method comprises following steps: preparing a quartz tube, wherein two ends ofthe quartz tube is a raw material end and a substrate end; placing an insulating substrate in the substrate end of the quartz tube, placing a raw material in the raw material end of the quartz tube; vacuumizing the quartz tube, then sealing the quartz tube until the pressure in the quartz tube reaches 10<-4> to 10 <-6> Pa, wherein the raw material is polyethylene or polypropylene; heating the rawmaterial end and the substrate end of the quartz tube for 0.5 to 1 hour, and then cooling the quartz tube in a furnace to 20 to 25 DEG C so as to form a graphene film on the insulating substrate, wherein the heating temperature of the raw material end is 1000 to 1150 DEG C, and the heating temperature of the substrate end is 200 to 900 DEG C. The provided method can prepare a graphene film that covers an insulating substrate with an area of 1 cm * 2 cm or larger according to the needs.

The invention discloses a double-layer film actuator and a preparation method thereof, and belongs to the field of functional materials and soft robots. A layer of regularly arranged metal hydroxide directionally grows on a polymer film substrate through a solid-state alkali self-sacrificing method to form a double-layer structure comprising a polymer film and transition metal hydroxide. The preparation method is simple and low in cost, and large-scale preparation can be realized. Rapid, remarkable and stable deformation capacity is achieved under the conditions of humidity change, heating, infrared light and the like by means of the difference of humidity response of the double-layer thin film, and moving and object grabbing can be achieved through deformation control. Therefore, the method has important application value in the fields of flexible switches, artificial muscles, soft robots, environmental monitoring and the like.

The invention relates to a preparation method of an all-inorganic lead-free metal halide perovskite nanowire and a high-performance infrared detection application of the nanowire. The nanowire is grown by a three-temperature-zone gas phase method, and the three temperature zones include the upstream source zone, the midstream source zone and the growth zone. A SnX2 source material is placed in theupstream source zone for providing a Sn source material; a CsX source material is placed in the midstream source zone for providing a CsX source material; a freshly stripped fluorophlogopite substrate is placed in the growth zone for growing the nanowire. A metal mask plate and electron beam evaporation are adopted for positioning and vapor deposition of metal electrodes to construct an infrareddetector. By means of the method, the new all-inorganic lead-free metal halide perovskite nanowire material which is free of toxicity, free of lead and environmentally friendly can be prepared, the forbidden band width is made continuously adjustable through energy band engineering, and effective response to near-infrared light is successfully realized. In the adopted chemical vapor deposition method, conditions are simple, and the cost is low. By adopting the electrode positioning method with the metal mask plate to prepare the infrared detector, the operation is convenient.

The invention discloses a manufacturing method of a down-conversion luminescent material. The manufacturing method comprises the forming steps that 1, multi-target magnetron sputtering equipment is provided; 2, a plurality of target materials are mounted and selected according to to-be-formed rare earth doped oxide, the matrix material of the rare earth doped oxide is rare earth vanadate or rare earth niobate, the target materials comprise matrix rare earth oxide targets, vanadium oxide targets or niobium oxide targets and doped rare earth targets, wherein the matrix rare earth oxide targets,the vanadium oxide targets or the niobium oxide targets correspond to the matrix material, and the doped rare earth targets correspond to a rare earth doped material; 3, a substrate is placed on a base sheet base of a co-sputtering reaction chamber; 4, vacuumizing is conducted on the co-sputtering reaction chamber; and 5, sputtering gas is introduced, and a sputtering technology with the substratetemperature being room temperature to 400 DEG C is conducted, so that the rare earth doped oxide is formed on the surface of the substrate. According to the manufacturing method of the down-conversion luminescent material, large area growth of the down-conversion luminescent material at the low temperature can be achieved, the manufacturing method can be compatible with a microelectronic technology, the technology of the manufacturing method is simple, the cost is low, and the manufacturing method can be effectively combined with the preparation process of solar cells.