32results about How to "High catalytic activity for oxygen evolution" patented technology

The invention discloses a sulphur vacancy richened Ni3S2 nanorod oxygen evolution electro-catalysis material and a preparing method and application thereof, and belongs to the field of electrolytic water catalysis. The preparing method comprises three steps that firstly, a precursor film layer is prepared through anodic oxidation treatment of a nickel sheet; secondly, the precursor film layer is subjected to annealing treatment to obtain oxygen vacancy richened NiO film layer; and finally, the film layer obtained after annealing is subjected to hydrothermal sulfidizing to obtain the sulphur vacancy richened Ni3S2 nanorod oxygen evolution electro-catalysis material. As the existence of the sulphur vacancy, energy barriers needing to be overcome by a midbody on adsorption or desorption on the catalyst surface are reduced, and the oxygen evolution catalytic performance is greatly improved. Sulphur vacancy richened Ni3S2 nanorods grow on a nickel substrate in situ, the resistance between acatalyst and the substrate is reduced, and meanwhile, the oxygen evolution catalyzing stability is improved. The method is simple in operation, the requirement for preparing equipment is low, the material is environment-friendly, the preparing method has generalizability, and the development and application of the transition metal sulfide catalyst are further promoted.

The invention relates to a method for preparing SPE (solid polymer electrolyte) anodic oxygen evolution catalysts for water electrolysis. The method mainly includes steps of dissolving precursors of metal salt, such as RuCl3, H2PtCl6, H2IrCl6 and the like, into ethanol / water solution, regulating the pH (potential of hydrogen) value of the solution by NaHCO3 ethanol / water, then ageing, separating, washing, roasting and the like, so that noble metal oxides with high oxygen evolution activity are prepared. Accordingly, the noble metal load amount is reduced, and cost of the SPE water electrolysis technology is lowered, and foundation for further commercialized application of the SPE water electrolysis technology is laid.

The invention relates to a flower ball-shaped nickel / cobalt oxide oxygen evolution catalyst, and a preparation method and application thereof. Concretely, nickel salt and cobalt salt are used as precursors; proper surfactants (such as DTAB (dodecyl trimethyl ammonium bromide) and CTAB (cetyltrimethyl ammonium bromide)) are added; the materials are dissolved into a small molecule organic solvent; under the participation of a coordination agent, the hydrothermal reaction is performed; the nickel / cobalt hydroxide nanometer material is prepared; through the steps of centrifugation washing, drying, roasting and the like, the nickel / cobalt oxide flower balls with the diameter being about 5mum are prepared. The nickel / cobalt oxides are applied to the oxygen evolution reaction in the water electrolysis hydrogen preparation process under the catalysis basic condition. The nickel / cobalt oxide obtained through preparation has large specific surface area; the appearance is controllable; the preparation process is simple; the conditions are mild; under the additional bias pressure, the method can be used for electrolysis pool water decomposition hydrogen preparation. The prepared nickel / cobalt oxide has good performance when being used as an alkaline solid polymer electrolyte (AEM) water electrolysis pool. The flower ball-shaped nickel / cobalt oxide oxygen evolution catalyst has wide application values in RFC (regenerative fuel cells), photoelectrocatalysis and electrolysis hydrogen generator devices.

The invention provides a preparation method of a foam metal-based lead alloy composite anode material. The preparation method comprises the following steps: treating the surface of a foam metal substrate and forming a tin-bismuth alloy layer on the surface of the foam metal substrate; then preparing a nano-oxide composite lead alloy; and then cladding the nano-oxide composite lead alloy onto the foam metal substrate with the tin-bismuth alloy layer on the surface by using a bimetal continuous extrusion cladding machine so as to prepare the foam metal-based lead alloy composite anode material for high-efficiency electrocatalytic oxygen evolution. The foam metal-based lead alloy composite anode material prepared by the invention gives full play to the high-efficiency electrocatalytic oxygenevolution activity of the nano-oxide composite lead alloy and the advantages of the foam metal substrate, and has the characteristics of light weight, good conductivity, high-efficiency electrocatalytic oxygen evolution performance, high corrosion resistance and the like, and can reduce resource consumption and save energy.

The invention relates to a preparation method of a long-life iridium-zirconium composite oxide inert anode. The preparation method involves an iridium-cerium-zirconium or iridium-tin-zirconium ternarycomposite oxide inert anode, and an iridium-cerium-rubidium-zirconium or iridium-tin-rubidium-zirconium quaternary composite oxide inert anode. The prepared anode consists of a titanium matrix and anoxide coating; and in the coating, zirconium dioxide and rubidium oxide are amorphous phases, iridium dioxide and tin dioxide are rutile phases, cerium dioxide is a fluorite phase, the conductivity of the anode is enhanced through addition of rubidium, precipitation of oxygen evolution active substances IrO2 crystals is promoted by adding zirconium, cerium doping plays a role in refining crystalgrains, the zirconium or the cerium is added to increase the active surface area of the anode, and doping of the zirconium, the cerium or the tin improves the corrosion resistance of the anode in a sulfuric acid system and thus prolongs the service life of the anode. The preparation process of the method is simple, the prepared anode has better oxygen evolution catalytic activity and a long service life, and in addition, as the noble metal iridium in the coating is replaced by non-noble metal, the production cost of the anode is reduced.

The invention discloses a preparation method of a gradient composite anode for nonferrous metals electrodeposition. The method comprises the following steps: preparing titanium bars by a drawing extrusion process; connecting a group of transverse titanium bars and three copper-coated titanium vertical bars to assemble into a fence-type titanium plate substrate; removing oil and carrying out activating treatment on the substrate by a chemical method, and preparing a nano-polyaniline-doped tin-antimony oxide by a coating method, and then carrying out argon arc welding on a fence-type titanium plate and a copper-coated titanium conductive beam; and respectively preparing an alpha-PbO2 intermediate layer and a molybdenum oxide-doped beta-PbO2 activating layer by an electrochemical codeposition method. The anode prepared by the method is good in electrocatalytic activity, low in cell voltage in electrodeposition, long in service life and low in energy consumption.

The invention discloses a method for preparing a manganese-cobalt composite material through cathodic electrodeposition. The method comprises the steps that electroplating liquid containing manganeseions and cobalt ions is added into an electroplating bath, a composite anode and a stainless steel cathode are inserted into the electroplating bath, and constant-current electroplating is carried outat indoor temperature for preset time, wherein the composite anode comprises, by mass, 10-30% of tin, 0.1-5% of cobalt and the balance lead. The working procedure of achieving electrodeposition of aMn-Co spinel coating on the stainless steel cathode can be complete in the same electroplating bath, no MnO2 is produced in the electrodeposition process, the influences of MnO2 particles impurities on the performance of the coating are reduced, and consumption of the manganese ions in the electroplating liquid is reduced.

The invention relates to a preparation method and application of NiFe-LDH oxygen evolution electrocatalytic material rich in cation vacancy. The preparation method includes the steps of (1) soaking Ni-Fe alloy matrix in electrolyte which contains, by weight, 1-3% of NaF, 4-7% of (NH4)2MoO4, 15-25% of H2O, 25-40% of glycerol and 25-55% of phosphoric acid; (2) subjecting the Ni-Fe alloy matrix soaked in the electrolyte to anodizing to obtain NiFeMo anodized film; (3) subjecting a sample treated in step (2) to alkaline liquid etching, washing, and drying to obtain the NiFe-LDH oxygen evolution electrocatalytic material. The NiFe-LDH oxygen evolution electrocatalytic material prepared herein has high catalytic activity and good electrochemical stability; the preparation method is simple, efficient and low in cost, is well popularizable and helps further promote the development and application of LDH catalysts.

The invention discloses an alloying method for obtaining an amorphous-layer or a crystalline-state and amorphous composite layer on a crystalline-state alloy surface by adopting pulsed arcs. A crystalline-state alloy matrix surface is instantaneously molten by applying pulsed arcs, and rapid solidification is realized under cooling of a cooling medium and a crystalline-state alloy matrix, so that the amorphous-layer or the crystalline-state and amorphous composite layer is obtained on the crystalline-state alloy surface. Compared with a conventional crystalline-state alloy, a crystalline-state alloy with the amorphous-layer or the crystalline-state and amorphous composite layer is prepared into an anode oxygen evolution electrode for electrolyzed water, so that oxygen evolution catalytic activity is better.

The invention provides a preparation method of a high specific surface area porous carbon doped iridium (HAPC / Ir) catalyst for water electrolysis for generating hydrogen, and belongs to the technicalfields of chemical power supply and new materials. According to the preparation method, MOF-5 is taken as the template, and the prepared material is applied to electrode materials. Through an impregnation method, iridium ions are merged to an organic frame made of MOF-5 through impregnation to obtain a precursor, and finally the precursor is made into the high specific surface area porous carbon doped iridium (HAPC / Ir) catalyst. The method and operation are simple, the equipment requirements are low, and high specific surface area porous carbon materials can be prepared massively. The technical process has the characteristics that the corrosion resistant performance of a positive electrode catalyst for water hydrolysis is enhanced in acidic electrolyte, and moreover, the stability of the catalyst is improved. Furthermore, the raw material (HAPC / Ir) is mild, nontoxic and safe, the resources of part materials are wide, and the industrial prospect is good.

The invention relates to a preparation method of a long-life iridium-zirconium composite oxide inert anode. The preparation method involves an iridium-cerium-zirconium or iridium-tin-zirconium ternarycomposite oxide inert anode, and an iridium-cerium-rubidium-zirconium or iridium-tin-rubidium-zirconium quaternary composite oxide inert anode. The prepared anode consists of a titanium matrix and anoxide coating; and in the coating, zirconium dioxide and rubidium oxide are amorphous phases, iridium dioxide and tin dioxide are rutile phases, cerium dioxide is a fluorite phase, the conductivity of the anode is enhanced through addition of rubidium, precipitation of oxygen evolution active substances IrO2 crystals is promoted by adding zirconium, cerium doping plays a role in refining crystalgrains, the zirconium or the cerium is added to increase the active surface area of the anode, and doping of the zirconium, the cerium or the tin improves the corrosion resistance of the anode in a sulfuric acid system and thus prolongs the service life of the anode. The preparation process of the method is simple, the prepared anode has better oxygen evolution catalytic activity and a long service life, and in addition, as the noble metal iridium in the coating is replaced by non-noble metal, the production cost of the anode is reduced.

The invention provides a device and method for removing hexavalent chromium from electroplating wastewater for electrocoagulation-electric flotation, wherein the device includes an electrocoagulation unit and a neutralization reaction unit arranged in sequence and communicated with each other, and a pump for pump is arranged beside the neutralization reaction unit An air compressor for feeding compressed air, a communication pipe for preventing liquid backflow is provided between the electrocoagulation unit and the neutralization reaction unit; a flow guide pipe for guiding compressed air is arranged in the neutralization reaction unit After the neutralization reaction unit, a first electric floating unit and a second electric floating unit are sequentially arranged, and the first electric floating unit is provided with a first interlocking electrode and a first three-phase separator; The second electric floating unit is provided with a second interlocking electrode and a second three-phase separator. The device and method provided by the invention have high electrical conductivity and low power consumption, can effectively reduce operating costs, do not need to add polymer flocculants, and can effectively improve the removal efficiency of hexavalent chromium and total chromium.

The invention provides a novel three-dimensional anode material for hydrogen production by water electrolysis. The novel three-dimensional anode material comprises nickel foam loaded N-doped carbon / transition metal oxide prepared in situ according to a liquid-solid synthesis method as well as a three-dimensional anode piece used for hydrogen production through water electrolysis. A preparation method of the three-dimensional anode material particularly comprises the following steps: (1) immersing clean nickel foam into a mixed solution, containing transition metal salt, a silicon source and a nitrogen source, of water and ethanol, taking out the nickel foam for airing, and repeating for three times; (2) calcining the nickel foam piece obtained in the step (1) for 1-6 h at 600-800 DEG C under the protection of inert gas, and then heating for 1-1.5 h at 200-250 DEG C in the atmosphere of O2, so as to obtain a nickel foam loaded N-doped carbon / transition metal oxide three-dimensional electrode. The three-dimensional electrode produced according to the preparation method has relatively low oxygen evolution overvoltage, has relatively high structural stability and oxygen evolution catalytic activity under long-term alkaline electrolysis condition, is simple in production process and adjustable in electrode component and variety, and has wide application prospects.

The invention discloses a sulphur vacancy richened Ni3S2 nanorod oxygen evolution electro-catalysis material and a preparing method and application thereof, and belongs to the field of electrolytic water catalysis. The preparing method comprises three steps that firstly, a precursor film layer is prepared through anodic oxidation treatment of a nickel sheet; secondly, the precursor film layer is subjected to annealing treatment to obtain oxygen vacancy richened NiO film layer; and finally, the film layer obtained after annealing is subjected to hydrothermal sulfidizing to obtain the sulphur vacancy richened Ni3S2 nanorod oxygen evolution electro-catalysis material. As the existence of the sulphur vacancy, energy barriers needing to be overcome by a midbody on adsorption or desorption on the catalyst surface are reduced, and the oxygen evolution catalytic performance is greatly improved. Sulphur vacancy richened Ni3S2 nanorods grow on a nickel substrate in situ, the resistance between acatalyst and the substrate is reduced, and meanwhile, the oxygen evolution catalyzing stability is improved. The method is simple in operation, the requirement for preparing equipment is low, the material is environment-friendly, the preparing method has generalizability, and the development and application of the transition metal sulfide catalyst are further promoted.

The invention relates to a preparation method of a double-effect oxygen electrode catalyst, in particular to the preparation method of a regenerable fueling battery oxygen electrode catalyst taking Pt as a basis. The method comprises the following steps: directly mixing a certain amount of H2IrCI6 and H2 PtCl6 into an organic solvent; adjusting the proportion of the H2IrCI6 and the H2 PtCl6; dripping the mixture onto a conductive matrix; and preparing an IrO2 Pt efficient catalyst through the thermal decomposition method, thereby not only the oxygen-evolution catalytic activity of the catalyst can be greatly improved, the electric potential can be reduced, and the availability of the catalyst is improved, but also the preparation process is simple, and no impurity enters; the prepared product can also be used for cathodic and anodic catalysts for other fuel batteries and other fields such as gas reforming, organic matter schizolysis, pollutant treatment, seawater electrolysis, and the like.

The present application relates to an oxygen evolution catalyst and its preparation method and application. The oxygen evolution catalyst is composed of nickel-cobalt metal oxide and mesoporous carbon, wherein the nickel-cobalt metal oxide is formed on the mesoporous carbon; the oxygen evolution The catalyst has good thermal stability and oxygen evolution catalytic activity.

The invention discloses a preparation method for a high-activity iridium-zirconium-series compound oxide anode for hydrometallurgy. The high-activity iridium-zirconium-series compound oxide anode comprises an iridium-zirconium binary compound oxide inert anode, an iridium-ruthenium-zirconium ternary compound oxide inert anode, an iridium-cobalt-zirconium ternary compound oxide inert anode, an iridium-molybdenum-zirconium ternary compound oxide inert anode, an iridium-rubidium-zirconium ternary compound oxide inert anode and an iridium-ruthenium-rubidium-zirconium quaternary compound oxide inert anode. The prepared anode consists of a titanium substrate and an oxide coating, the zirconium dioxide and the rubidium oxide in the coating are amorphous phases, the iridic oxide and the rutheniumdioxide are rutile phases, the cobaltosic oxide is the spinel phase, the molybdenum trioxide is an alpha phase, the adding of the zirconium, or ruthenium or cobalt increases the oxygen evolution activity surface area of the anode, the anode activity is improved, and the adding of the rubidium or molybdenum improves the conductivity of the anode. The preparation method is simple in preparation process, the prepared anode has higher oxygen evolution catalytic activity and longer service life, and as the precious metal iridium element in the coating is replaced by the non-precious metal, the production cost of the anode is reduced.

The invention relates to a preparation method and application of a hydrothermally assisted iron oxyhydroxide-nickel-iron hydrotalcite integrated electrode applied in an alkaline medium; the electrode is used to catalyze oxygen evolution in the process of electrolyzing water to produce hydrogen under alkaline conditions reaction. Advantages: The morphology of highly dispersed nickel-iron hydroxide integrated electrode is controllable; the preparation process is simple and the conditions are mild; it is used in water electrolysis cells to split water and produce hydrogen under external bias voltage. The highly dispersed iron oxyhydroxide / nickel-iron hydrotalcite integrated electrode prepared by the invention has good performance when used as an alkaline solid polymer electrolyte (AEM) water electrolysis cell. The invention has wide application value in renewable fuel cell (RFC), photoelectric catalysis and electrolysis hydrogen generator devices.