The invention belongs to the field of
scheelite-structure luminescent materials, relates to a research on novel composite
tungsten molybdate phosphors which are NaEu(MoO4)2-x(WO4)x-type fluorescent microcrystals, and especially relates to a
chemical solution preparation method of the NaEu(MoO4)2-x(WO4)x-type fluorescent microcrystals. The NaEu(MoO4)2-x(WO4)x-type fluorescent microcrystals have a general formula of NaEu(MoO4)2-x(WO4)x, wherein x is greater than or equal to 0 and less than or equal to 2. The
chemical solution preparation method comprises the following steps of weighing Na2MoO4 and Na2WO4 solutions having corresponding volumes according to a
mole ratio of all raw materials for preparation of a certain amount of the NaEu(MoO4)2-x(WO4)x-type fluorescent microcrystals as a target
system, putting the weighed Na2MoO4 and Na2WO4 solutions into a Teflon
beaker with a stirrer, respectively adding a corresponding amount of an EuCL3 solution into the Teflon
beaker, stirring at a normal temperature for 15 to 30 minutes, adjusting a pH value to 6-9, putting the Teflon
beaker into a high-
pressure reactor, carrying out a
hydrothermal reaction process at a temperature of 80 to 160 DEG C for 15 to 30 hours, naturally cooling to a
room temperature, carrying out
centrifugal separation of precipitates, washing by deionized water, and
drying at a temperature of 100 to 150 DEG C to obtain the NaEu(MoO4)2-x(WO4)x-type fluorescent microcrystals. The
chemical solution preparation method adopts simple
process equipment and allows a low
reaction temperature.
Rare earth-doped
tungsten molybdate fluorescent microcrystals obtained by the chemical solution preparation method have a pure phase, a uniform and appropriate particle size and regular morphology, can emit high purity and high brightness
red light, and have good practicality.