The invention discloses a method for solving oxidation material rushing-out in preparation for
oxalic acid by virtue of
starch, comprising the following steps of: (1) hydrolyzing the
starch in an acidic condition to prepare a
monosaccharide liquid; (2) adding an
oxalic acid crude product centrifugal mother liquid in a reaction container with an added amount which is 1 / 3-1 / 2 of the whole reaction volume, replenishing concentrated sulphuric acid in a volume which is 5-20% of the total volume of the
monosaccharide liquid and a catalyst simultaneously, and then adding an initiator; and adjusting the temperature of the
reaction system to be above 50 DEG C, and adding
nitric acid in a volume by
volume concentration of 50-90%; and (3) immediately adding the
monosaccharide liquid obtained in the step (1) after the
nitric acid and the initiator start to react, and enabling the
nitric acid and saccharides to start to react, so as to generate the
oxalic acid. The method disclosed by the invention has the beneficial effects that the material rushing-out phenomenon generated by the directly serious
initiation of monosaccharides and the nitric acid during an
initiation process in the starting phase of the traditional preparation for oxalic acid by virtue of a
starch-nitric
acid oxidation process is avoided, and the production potential safety hazards brought by the material rushing-out phenomenon aforementioned are thoroughly solved; and moreover, the method is extremely low in
investment cost without influence on the cost of the oxalic acid, high in safety, convenient to operate and extremely easy to popularize.