This invention discloses a method for preparing monolithic SiC
nanowire aerogels via in-situ carbothermal reduction, as well as the SiC
nanowire aerogels prepared by this method and their applications, belonging to the field of advanced
ceramic materials and
aerogel preparation technology. This method uses
biomass-derived
cellulose fibers as the
carbon source and three-dimensional template,
silica nanoparticles as the
silicon source, and NH4Cl as a volume shrinkage inhibitor. Through precursor preparation, freeze-
drying, carbothermal reduction, and post-treatment steps, the controllable preparation of monolithic SiC
nanowire aerogels is achieved. This invention features a simple, green, and economical process, is easily scalable, and allows for near-net-shape forming of complex shapes through mold design. The prepared
aerogel has a three-dimensional interwoven nanowire
network structure with a
porosity as high as 99.7% and a
thermal conductivity as low as 0.045 W / (m·K). It also exhibits excellent superelasticity, high-temperature stability, and high-efficiency
oil absorption capacity, making it suitable for applications such as
aerospace high-temperature insulation,
energy system protection, and
oil pollution treatment.