The invention relates to an energy storage niobate microcrystalline glass dielectric material and a preparation method thereof. The preparation method comprises the following steps of: preparing BaCO3, SrCO3, Na2CO3, Nb2O5, SiO2, B2O3, TiO2 and BaF2 serving as initial raw materials in a ratio of aNa2O3, bSrO, cBaO, dNb2O5, eSiO2, fB2O3 and gXY2 (X is Ti or Ba, and Y is O or F), ball-milling and mixing for 6 hours, drying, melting at the high temperature of between 1,530 and 1,550 DEG C for 2 to 3 hours, quickly cooling, annealing to obtain high-density uniform glass, and performing controlled crystallization at a certain temperature to obtain the microcrystalline glass dielectric material. The relative dielectric constant of the microcrystalline glass dielectric prepared by the method is adjustable in the range of 30 to 100, and the maximum direct-current breakdown field strength is 1,500kV / cm.