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96results about How to "Breakdown field strength" patented technology

Nanofiber/PVDF (polyvinylidene fluoride) compound medium with sandwich structure and preparation method of nanofiber/PVDF compound medium

The invention belongs to the field of a compound medium and particularly relates to a nanofiber / PVDF (polyvinylidene fluoride) compound medium with a sandwich structure and a preparation method of the nanofiber / PVDF compound medium. Upper and lower layers of the sandwich structure of the compound medium are PVDF films, a middle layer is a CFO@BZT-BCT NFs / PVDF compound medium film, and the three layers of structure media are combined through hot pressing, wherein the PVDF films are prepared with a solution tape casting method through quenching treatment, and the CFO@BZT-BCT NFs / PVDF compound medium film is prepared through steps as follows: crystalized BZT-BCT NFs is prepared from a BZT-BCT spinning precursor through electrostatic spinning and high-temperature calcination, CFO is introduced, CFO@BZT-BCT NFs is prepared and subjected to surface modification with dopamine hydrochloride, finally, CFO@BZT-BCT NFs is mixed with PVDF, suspension turbid colloid is prepared and subjected to solution tape casting and quenching treatment, and the nanofiber / PVDF compound medium is prepared. The technical problems of low energy density and high dielectric loss of an inorganic filling phase / polymer based compound medium are solved.
Owner:HARBIN UNIV OF SCI & TECH

Stimulated experiment system for gas detonation by human body electro-static discharge

The invention discloses a stimulated experiment system for gas detonation by human body electrostatic discharge, comprising a mixed gas cavity and an ignition device positioned in the mixed gas cavity, wherein the ignition device is controlled by a human body ESD (Electro-Static Discharge) model and carries out ignition; the mixed gas cavity is communicated with a gas tank through an electromagnetic valve and is connected with an oxygen concentration sensor, a gas concentration sensor and a temperature sensor, the human body ESD model, the ignition device, the oxygen concentration sensor, the gas concentration sensor and the temperature sensor are all connected with a computer control system, and the computer control system is connected with a display device. The system of the invention excites gas in the mixed gas cavity to carry out detonation through the human body ESD model and accurately provides values of gas concentration and oxygen concentration upon gas detonation through the infrared gas concentration sensor, an infrared analyzer, the oxygen concentration sensor and the like, thus both the technical support for human body electro-static safe protection in coal mine environment and the foundation for manufacturing electrostatic preventing working uniform of miner are offered.
Owner:ZHONGYUAN ENGINEERING COLLEGE

Sodium bismuth titanate-based ferroelectric ceramic as well as preparation method and application thereof

The invention relates to a sodium bismuth titanate-based ferroelectric ceramic as well as a preparation method and the application thereof. A general chemical formula of the sodium bismuth titanate-based ferroelectric ceramic is (1-x)[0.9(0.94Na0.5Bi0.5TiO3-0.06BaTiO3)-0.1NaNbO3]-xZn, wherein x in the formula is greater than or equal to 0 and less than or equal to 0.01. The preparation method comprises the following steps: firstly, preparing all raw material components according to the stoichiometric ratio, then uniformly mixing all the raw material components and carrying out pre-sintering and grinding in sequence to obtain a ground powder body; secondly, carrying out granulating to obtain a granulated powder body; thirdly, carrying out dry pressing and cold isostatic pressing to obtain a densified ceramic green body, carrying out adhesive removal on the densified ceramic green body, and then sintering to obtain the sodium bismuth titanate-based ferroelectric ceramic. According to the preparation method disclosed by the invention, by doping zinc in the sodium bismuth titanate-based ferroelectric ceramic, the breakdown strength and a saturation polarization value of the sodium bismuth titanate-based ferroelectric ceramic are improved, the energy storage density and the stability are improved, leakage current is reduced, growth orientation of crystals is benefited as well as development and application of high-power and high-capacity storage capacitors are facilitated.
Owner:INNER MONGOLIA UNIV OF SCI & TECH

KNN-based (sodium potassium niobate-based) energy storage microcrystalline glass material with ultralow dielectric loss and preparation method

The invention relates to a KNN-based (sodium potassium niobate-based) energy storage microcrystalline glass material with ultralow dielectric loss and a preparation method. The microcrystalline glass material is prepared from a glass phase and a crystal phase through mixing, fusing, cooling and molding, annealing, carrying out crystallization heat treatment, wherein according to mol percent, the glass phase accounts for 20 percent to 50 percent and the balance is the crystal phase; the crystal phase is composed of K2CO3, Na2CO3, Nb2O5 and BaCO3 at a mol ratio of (3-x) to (3-x) to 6 to 2x and x is more than 0 and less than or equal to 2.5. The KNN-based energy storage microcrystalline glass material prepared by the preparation method has extremely low dielectric loss; BaO is introduced, has the effect of adjusting the composition of the crystal phase of a sodium potassium niobate system and also has a certain promotion effect on a devitrification process and devitrification is accelerated by rare-earth metal ions; the BaO can also generate a pinning effect, and adverse impacts, caused by interface polarization, on breakdown and worsening are weakened; finally, the microcrystalline glass material with a high dielectric constant is obtained.
Owner:SHAANXI UNIV OF SCI & TECH

Dielectric composite material and preparation method thereof

The invention relates to a dielectric composite material and a preparation method thereof. The preparation method is characterized by comprising the following steps: carrying out hydroxylating treatment on the surfaces of barium titanate particles, then adding fluorine-containing monomers to initiate polymerization, and obtaining modified barium titanate with a core-shell structure; then using themodified barium titanate and a vinylidene fluoride-hexafluoropropylene copolymer to prepare and obtain an electrostatic spinning solvent, and then utilizing an electrostatic spinning process to obtain the dielectric composite material. The dielectric composite material and the preparation method have the beneficial effects that the barium titanate particles have a high dielectric constant, the vinylidene fluoride-hexafluoropropylene copolymer has a good breakdown property; by introduction of the fluorine-containing monomers, the monomer molecular chains have a certain quantity of fluorine atoms and are similar to a matrix polymer PVDF-HFP (Polyvinylidene Fluoride-Hexafluoropropylene) respectively, and the surfaces of the particles are coated with the monomers, so that the effect of mild transition is achieved, the compatibility between the particles and the matrix can be improved, further the particles have good dispersity, and the dielectric composite material has a high dielectric constant, high breakdown field strength and low dielectric loss.
Owner:RESEARCH INSTITUTE OF TSINGHUA UNIVERSITY IN SHENZHEN

Bismuth barium sodium niobate-based glass ceramic material with high energy storage density, and preparation method and application thereof

The invention relates to a bismuth barium sodium niobate-based glass ceramic material with high energy storage density, and a preparation method and application thereof. The chemical components of theglass ceramic material accord with a chemical general formula of 21.6BaCO3-2.4Bi2O3-6Na2CO3-30Nb2O5-40SiO2. The preparation method comprises the following steps: taking BaCO3, Bi2O3, Na2CO3, Nb2O5 and SiO2 as raw materials to carry out uniform mixing, then carrying out drying, carrying out melting at a high temperature to obtain a glass melt; quickly pouring the high-temperature melt into a preheated mould, removing residual stress in the glass body through annealing treatment, and then cutting the glass block body into glass sheets with a same size and thickness; and carrying out controlledcrystallization on the glass sheets to obtain the glass ceramic energy storage material. Compared with the prior art, the glass ceramic energy storage material prepared by the method has the advantages of high dielectric constant (up to 118), high breakdown field strength (up to 1878.75 kV/cm), high energy storage density (up to 18.4 J/cm<3>), low loss (low to 0.025), good temperature stability and the like.
Owner:TONGJI UNIV

Longitudinal tensile insulating dielectric electrical property measuring device and measuring method thereof

The invention provides a longitudinal tensile insulating dielectric electrical property measuring device and a measuring method thereof. The longitudinal tensile insulating dielectric electrical property measuring device is characterized by comprising a high voltage power supply, a support frame, a fixing seat disposed on the support frame, a limiting plate matched with the fixing seat and disposed on the lower portion of the fixing seat, a rotating shaft respectively connected with the supporting frame and the limiting plate and located below the limiting plate, an upper electrode member anda lower electrode member sequentially connected with the rotating shaft, a driving assembly for pulling the lower electrode member and a hollow sealing cavity covering the upper electrode member and the lower electrode member. The device has the advantages of achieving the measurement of breakdown field strengths of an insulating dielectric original sample and the sample after stretched in the directions of an upper electrode and a lower electrode, breaking through the limitation that the tested insulating dielectric sample can only be transversely stretched, and achieving the simulated measurement of the insulating dielectric sample under tensile and pressure states.
Owner:HARBIN UNIV OF SCI & TECH

High-temperature energy storage hybrid polyetherimide dielectric film and preparation method and application thereof

The invention provides a high-temperature energy storage hybrid polyetherimide dielectric film and a preparation method and application thereof, and belongs to the technical field of polymer capacitor films, and the preparation method comprises the following steps: reacting a polyetherimide monomer with a hydroxyl functional group to synthesize a polyetherimide acid solution with a hydroxyl end group or a side chain; then adding water and metal alkoxide as inorganic component precursors into the polyetherimide acid solution to form uniform sol, and preparing the thin film through film coating and thermal imidization treatment. The dielectric film is prepared by a one-step synthesis method, and an inorganic phase is introduced in a hybridization process, so that molecular-level dispersion is realized, agglomeration of the inorganic phase and interfacial compatibility with an organic phase are improved, and the energy storage performance of the dielectric film at high temperature is improved. The energy storage density of the obtained hybrid dielectric material can reach 3.0-3.64 J/cm < 3 > at the temperature of 200 DEG C and the efficiency of 90%, and the energy storage density is greatly higher than that of an existing dielectric. The breakdown strength, the leakage current, the glass transition temperature and other properties are all improved, and the comprehensive dielectric property is good.
Owner:TSINGHUA UNIV

Bismuth ferrite-based ternary solid solution dielectric film material and preparation method thereof

The invention provides a bismuth ferrite-based ternary solid solution dielectric film material and a preparation method thereof and belongs to the technical field of dielectric materials. The chemicalcomponent general formula is (1-x-y)BiFeO3-xBaTiO3-ySrTiO3, wherein x and y are molar fractions, and x is greater than 0 and less than 1, y is greater than 0 and less than 1 and x+y is greater than 0and less than 1. The preparation method comprises the steps of mixing raw materials of Bi2O3, Fe2O3, BaCO3, SrCO3 and TiO2 according to a selected chemical metering ratio to obtain a raw material powder; presintering the raw material powder to obtain a ceramic blank; burying and sintering the blank to obtain a ceramic target material; finally carrying out pulsed laser deposition and annealing treatment on the ceramic target material so that the bismuth ferrite-based ternary solid solution dielectric film material can be obtained. Experiments prove that the breakdown field strength of the bismuth ferrite-based ternary solid solution dielectric film material can reach 3.0-5.3 MV/cm, the energy storage density of the bismuth ferrite-based ternary solid solution dielectric film material can reach 112 J/cm<3>, the energy storage efficiency of the bismuth ferrite-based ternary solid solution dielectric film material is about 80%; the bismuth ferrite-based ternary solid solution dielectric film material is a novel environmentally friendly lead free dielectric material with excellent properties such as higher dielectric constant, smaller dielectric loss, strong polarization, high breakdown and high energy storage density.
Owner:TSINGHUA UNIV

Strontium barium niobate-based glass ceramic energy storage material and preparation method thereof

The invention relates to a strontium barium niobate-based glass ceramic energy storage material and a preparation method thereof. The strontium barium niobate-based glass ceramic energy storage material is prepared from BaCO3, SrCO3, Nb2O5, SiO2, Al2O3 and B2O3 in a molar ratio of 20:20:20:(30-35):5:(0-5). The preparation method of the strontium barium niobate-based glass ceramic energy storage material comprises the following steps: carrying out ball milling and mixing, drying, then melting at high temperature, rapidly pouring high-temperature melt into a copper mould to be moulded, then carrying out stress relief annealing, cutting into glass slices with the thickness of 1.5mm, and finally carrying out controlled crystallization, so that the strontium barium niobate-based glass ceramic energy storage material is obtained. Compared with similar materials, the strontium barium niobate-based glass ceramic energy storage material has excellent machining property and can be processed into slices with the thickness below 150Mum through mechanical polishing, thereby being convenient for follow-up processing of small devices; meanwhile, the strontium barium niobate-based glass ceramic energy storage material has excellent dielectric property and resistance to breakdown field strength, and energy storage density of the strontium barium niobate-based glass ceramic energy storage material can reach 7.4J / cm<3>.
Owner:TONGJI UNIV

Industrial-frequency alternating-current anodic oxidation method of anode aluminum foil for aluminum electrolytic capacitor

The invention discloses an industrial-frequency alternating-current anodic oxidation method of an anode aluminum foil for an aluminum electrolytic capacitor and belongs to the technical field of the aluminum electrolytic capacitor. The industrial-frequency alternating-current anodic oxidation method comprises the following steps: firstly respectively connecting the two poles of an industrial-frequency alternating-current power supply with respective etched aluminum foils; subsequently dipping into a formation electrolyte to perform anodic oxidation treatment, and still performing constant-voltage anodic oxidation treatment for 5min to 20min after the impressed voltage is increased to a set voltage; finally thermally treating the aluminum foils which are subjected to the anodic oxidation treatment so as to form an Al2O3 medium film on the surface of each etched aluminum foil. Compared with an etched aluminum foil prepared by means of direct-current anodic oxidation at the same withstand voltage, the etched aluminum foil prepared by the method disclosed by the invention is 1% to 5% higher in specific volume value, 1% to 3% lower in loss value, 0.004-0.008microamp.V<-1>.microfarad<-1> in leakage current parameter K value range, and 30% to 90% higher in production efficiency.
Owner:XI AN JIAOTONG UNIV

Medium-voltage ethylene propylene rubber insulating material and preparation method thereof

The invention discloses a medium-voltage ethylene propylene rubber insulating material and a preparation method thereof. The medium-voltage ethylene propylene rubber insulating material comprises the following components in percentage by weight: 15-30 percent of ethylene-propylene-diene rubber, 9-20 percent of ethylene-propylene rubber, 4-10 percent of linear low-density polyethylene, 4-7 percentof zinc oxide, 0.1-0.4 percent of stearic acid, 5-35 percent of superfine talc powder, 4-7 percent of paraffin hydrocarbon oil, 0.5-3 percent of paraffin, 10-30 percent of calcining clay, 0.1-0.9 percent of surface active agent gamma-aminopropyltriethoxysilane, 0.4-1.8 percent of antiager 4,4'di(alpha,alpha dimethylbenzyl)diphenylamine, 0.5-1.5 percent of vulcanizer dicumyl peroxide and 0.3-1.4 percent of vulcanizing agent triallyl cyanurate. By synthesizing the performance of various materials and learning from strengths to offset their weaknesses, the aims of reducing the cost and improvingthe electric performance are achieved. Tests prove that the medium-voltage ethylene propylene rubber insulating material disclosed by the invention has the volume resistivity of 1014 ohm.m and the breaking-down field strength of larger than 30KV / mm and has the advantages of excellent electric performance, higher thermal ageing performance and physical and mechanical performance, simple preparation process and strong operability.
Owner:JIANGSU HENGTONG POWER CABLE +1

Niobium-silicon-based glass energy storage material with high energy storage density and preparation and application thereof

The invention relates to a niobium-silicon-based glass energy storage material with the high energy storage density and preparation and application thereof. Batching is conducted according to the mole ratio 25.6:6.4:32:36 of BaO to R(2)O to Nb2O5 to SiO2, wherein R is alkali metal or alkaline-earth metal; BaCO3, R2CO3, Nb2O5 and SiO2 are weighed, ball-milled and mixed to be uniform, high-temperature melting is conducted, and a high-temperature melt is obtained; after being clarified for a period time at constant temperature, the high-temperature melt is poured into a preheated metal mold, quenching molding and stress relief annealing are conducted, and then the niobium-silicon-based glass energy storage material with the high energy storage density is obtained; the obtained glass is cut into sheets with the thickness of 0.9-1.2 mm, grinding and polishing are conducted, and the obtained sheets can be applied to an energy storage capacitor material. Compared with the prior art, the preparation technology is simple, the complex aftertreatment step is not needed, the prepared glass energy storage material has the high dielectric constant of 17-23, the average breakdown-resistant field strength is 2,600-3,420 kV/cm, the energy storage density of the material is 6.7-11.1 J/cm<3>, and the material can be applied to the energy storage capacitor material.
Owner:TONGJI UNIV
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