The invention provides a memristor device based on an organic ferroelectric film material, comprising a flexible substrate, a bottom electrode formed on the flexible substrate, an organic ferroelectric film layer formed on the bottom electrode, and an upper electrode formed on the organic ferroelectric film layer, wherein the organic ferroelectric film layer is made of a vinylidene fluoride based ferroelectric polymer. The memristor device can achieve multi-state storage, has a memristive performance, has good mechanical property of being compatible with electronic skin, can simulate the functions of biological nerve synapses, has the advantages of small size, simple structure, low cost, non-volatility, quick reading and writing and the like, and provides the possibility of preparing a light, flexible and integrated artificial cognition equipment in the future. The invention further provides a method for preparing the memristor device based on an organic ferroelectric film material.