The application relates to the field of
high polymer material and
film processing technology, in particular to a forming and
processing technology of a biaxially stretched
polymer film; the technology comprises the steps of
inorganic particle surface modification, esterification, polycondensation,
melt extrusion casting and biaxial stretching and winding; the technology combines specific
monomer copolymerization to provide main chain rigidity and steric hindrance, and cooperates with multifunctional crosslinking monomers to build a slightly long branched and micro-crosslinked structure in the
system; the core is to introduce an
end group reaction agent and a macromolecular
antioxidant to close the polar
end group to inhibit degradation, and to combine the
surface modified nanoparticles with the
monomer containing a
sulfonate group to form a polar
ion aggregate in the amorphous region; the application overcomes the defects that the traditional process lacks a main chain rigidity cooperative design and an
end group closing mechanism, causes a significant increase in
thermal shrinkage and a decrease in
dielectric performance in a high temperature and
high frequency scene, improves the thermal dimensional stability of the material, and improves the
dielectric breakdown strength and the surface
metal layer adhesion.