The invention belongs to the technical field of
high polymer materials, and particularly relates to a preparation method of double-terminated
polysulfone, thepreparation method comprises the following steps: taking
bisphenol A and 4, 4 '-dichlorodiphenyl
sulfone as reaction monomers, adding an end-capping
reagent A with activity lower than that of the
bisphenol A, a salt-forming agent and a
solvent for reaction until the molecular weight reaches the target molecular weight, adding an end-capping
reagent B with activity higher than that of the
bisphenol A for
continuous reaction, and after the reaction is finished, carrying out post-treatment to obtain the double-terminated
polysulfone. The end-capping
reagent A with activity lower than that of
bisphenol A is added in the early stage of the reaction to reduce the low molecular weight
polymer part in the final product so that the
mechanical property,
heat resistance,
thermal stability and other properties of the product are improved. When the reaction is about to be finished, the end-capping reagent B with higher activity than
bisphenol A is added so that the molecular weight is controlled through rapid end capping, the performance of products in different batches can be more stable, and the method is more suitable for the field of preparation of hollow
fiber membranes.