The invention discloses preparation methods for porous nano antibacterial particles and a composite hollow membrane and the composite hollow membrane. The preparation method for the porous nano antibacterial particles comprises the steps: adding
titanium tetrachloride into water, adding
ammonium sulfate and concentrated
hydrochloric acid, carrying out stirring, then, carrying out heating-up and heat preserving, and adding stronger
ammonia water for cooling; adding beta-
cyclodextrin, and carrying out stirring, so as to obtain glue; subjecting the glue to a
hydrothermal reaction, so as to obtaintitanium dioxide
nanoparticle sol; adding CuCl2 and
sodium dodecylbenzene sulfonate into the particle
sol, carrying out stirring, then, adding a
reducer and pure water, and carrying out mixing, so asto obtain a reactant; subjecting the reactant to a
light induced reaction, so as to prepare
copper-coated
titanium dioxide nanoparticles; and washing the
copper-coated particles, carrying out baking,and then, carrying out
calcination, thereby preparing the porous
copper-coated
titanium dioxide nano antibacterial particles. The composite hollow-
fiber filter membrane prepared by using the particles is high in water flux, high in
porosity, resistant to bacterial
contamination and easy to clean and can be extensively applied to the fields of
sewage and
water treatment, material concentrating, pretreatment of
brackish water and
seawater desalinization, and the like.