The invention relates to high-purity steel and a production process, and belongs to the technical field of steel production. The production process comprises the procedures of carrying out converter primary smelting, carrying out LF refining, carrying out VD vacuum treatment and carrying out continuous casting, the LF refining procedure comprises the following steps that (21) online bottom argon blowing is carried out when the steel enters a station, the argon flow is 120-140L/min, and the Ar pressure is 0.35-0.4MPa; (22) a slag former and a deoxidizing agent are added for first-time electrifying slagging, 6-level voltage is adopted, the current is 28000-30000A, the argon flow is 280-300L/min, the argon pressure is 0.35-0.4MPa, sampling is conducted after slagging is conducted for 8-12min through power transmission heating, and alloy is added to adjust components; the slag former comprises 4.5-7.2kg of calcite per ton of steel, 0.7-1.1kg of fluorite per ton of steel and 0.3-0.5kg of bauxite per ton of steel; and (23) after the components are adjusted, secondary electrifying is conducted, 4-level voltage is adopted, the current is 32000-34000 A, the argon flow is 70-90L/min, the Ar pressure is 0.3-0.35MPa and when the temperature of molten steel is greater than or equal to 1670 DEG C, a silicon-calcium wire is fed. The high-purity steel and the production process have the effects of reducing the impurity content in the molten steel and improving the purity of the molten steel.