The invention discloses a collagen polypeptide nanosphere surface positive charge modification method. The method includes: dispersing collagen polypeptide nanospheres in
distilled water, adding Al2(SO4)3 under stirring, carrying out stirring reaction, then regulating the pH value of the
system to 3.5-5.0, further carrying out stirring reaction, and performing
centrifugation and separation to obtain Al<3+> modified collagen polypeptide nanosphere; dispersing the Al<3+> modified collagen polypeptide nanosphere in
distilled water, adding a strong positive charge material under stirring, adjusting the pH value of the
system to 4-7, introducing
nitrogen for protection, adding an initiator, carrying out stirring reaction,
centrifugation, separation, and freezing
drying, thus obtaining the positive charge
surface modified collagen polypeptide nanosphere. According to the aluminum tanning principle in a tanning
chemical process, cations with good binding capacity with
fluorine ions are introduced through reaction of Al<3+> and collagen polypeptide nanospheres, also the strong electropositive compound is further introduced through Michael
addition reaction, and the excellent performance of nanoparticles is combined so as to effectively adsorb and separate fluorinions in
wastewater.