The invention discloses a preparation method of a nitrogen-rich covalent organic framework material connected by full conjugated carbon-carbon double bonds, and relates to the technical field of covalent organic framework material preparation. The method comprises the following steps: adding 1,3,5-trimethyl-2,4-dicyanopyridine, 2,4,6-tris(p-aldehyde phenyl)-1,3,5-triazine, anhydrous piperidine andanhydrous N,N-dimethylformamide into a pressure bottle, carrying out a reaction of the materials by heating under argon gas protection, collecting a solid by a vacuum filtration method after the reaction is completed, washing the solid with dichloromethane and water, and collecting the solid and then performing vacuum drying for 24 h to obtain a yellow solid product, namely the nitrogen-rich covalent organic framework material connected by full conjugated carbon-carbon double bonds. The preparation method has the advantages of simple equipment, convenient operation, simple and easy synthesissteps and low cost, and the prepared material has a regular pore structure, rich active sites, and efficient electron conduction capability.