The invention discloses a
cement calcination harmless process based on waste
cathode carbon block alternative fuel, which comprises the following steps: after electrolytic aluminum waste
cathode carbon blocks are subjected to
magnetic separation to remove iron and are ground into 80 mu m
sieve residue less than or equal to 12 percent, pre-mixing with pretreated
Bayer process red mud (Al2O3 is more than or equal to 18 percent by weight and Na2O is less than or equal to 6 percent by weight) according to a
mass ratio of 100: (3-8) to form composite fuel; the fuel is sprayed into a decomposing furnace through a multi-channel
combustor, and stays at 860-900 DEG C for more than or equal to 5 seconds to replace 15-35% of fire
coal; after
combustion, the
raw material stays for 25-40 minutes in a high-temperature zone of 1420-1450 DEG C of the
rotary kiln, so that
fluorine ions react with Al2O3 in the
red mud to generate a Na3AlF6 mineral phase; the
kiln tail flue gas is suddenly cooled to below 180 DEG C within 0.8 second through a quench
tower to inhibit dioxin, and then
carbide slag (Ca / F
molar ratio is 1.5-2.2) is sprayed to remove residual
fluorine; and returning the defluorinated dust to the raw mill for cyclic utilization. According to the technology, the
fluorine curing rate is larger than or equal to 95%, the dioxin emission is smaller than or equal to 0.025 ng-TEQ / Nm < 3 >, the clinker
coal consumption per
ton is smaller than or equal to 95 kgce, and the problems of
pollution control and energy efficiency optimization in the waste
cathode carbon block fuelization process are solved.