The invention provides a supported
zinc-
calcium complex as well as a preparation method and application thereof. By adopting the one-step leaching method of the
carbide slag and the
zinc oxide ore,
ammonia released when the
carbide slag is dissolved under the action of
ammonium chloride is fully utilized, and
zinc ions in the zinc
oxide ore are leached by utilizing the
ammonia component, so that the situation that
ammonia water is additionally added when the zinc
oxide ore is leached can be avoided, and the preparation process is simplified; meanwhile, zinc and
calcium refined
clear liquid obtained through leaching is subjected to a one-step
pyrolysis and
carbonization method, the interaction between free ammonia generated during
pyrolysis of the zinc-ammonia complex and ammonia consumed during
carbonization of soluble
calcium is fully utilized, additional addition of ammonia during calcium
carbonization is avoided, and the
energy consumption of ammonia
distillation of the zinc-ammonia complex is reduced; the preparation method is simple in technological process, and the cost of the
calcium carbonate carrier and ammonia is greatly reduced; meanwhile, the leaching liquid
ammonium chloride and the
carbon dioxide can be recycled, so that the input cost of the leaching liquid and the
carbon dioxide is reduced, and the emission of
nitrogen-containing waste liquid is reduced.