The application belongs to the technical field of membrane separation, and particularly relates to a
composite membrane and a preparation method and device thereof, which comprises the following steps: S1, a macroporous
neutral charge base membrane is selected, a supporting substrate is used to support the base membrane, and the base membrane is assembled into a
polytetrafluoroethylene diffusion cell to divide the
diffusion cell into two independent chambers; S2, a ligand solution is prepared and injected, and a
metal organic framework precursor solution is prepared according to a 1:1
molar ratio;
metal organic framework materials with sub-nanometer channels are synthesized in-situ in membrane holes through
diffusion effects of two specific ligands in the membrane holes, and the membrane holes of the base membrane are filled with the materials to prepare a high-performance
composite membrane, the synthesis process of the membrane material avoids inevitable
surface charges and defects of the
metal organic framework materials in a traditional membrane preparation method, the
mechanical strength of the
composite membrane is improved by introducing a
polymer base, and the sub-nanometer channels of the
neutral charge metal organic framework materials are used for
lithium-
magnesium separation.