The invention relates to a citric acid composite disinfectant, which is composed of mixed components of, by weight: 12 to 32 parts of organic chlorine, 3 to 13 parts of citric acid, and 55 to 85 parts of sodium sulfate. When in use, according to different demands, the composite disinfectant can be dissolved with water, and can be diluted to a required concentration. After the composite disinfectant is dissolved, good sterilizing efficacy is maintained, disinfection effect is substantially improved, irritating odor is small, and stability of the product is enhanced. The product is safe and environment protecting, and has characteristics of broad spectrum and high efficiency. The product has substantial killing effects against pathogenic microorganisms such as foot-and-mouth disease virus, swine fever virus, swine vesicular disease virus, Newcastle disease virus, bursa disease virus, escherichia coli, and staphylococcus.