The invention discloses a manufacturing method of mirror oriented silicon steel. The manufacturing method of the mirror oriented silicon steel comprises the steps that molten iron is smelted, one or more elements of Sb, Sn, P, Cu and Bi are added in the smelting process, and after the molten steel is refined and poured, a plate blank is obtained; after the plate blank is heated to 1320 DEG C-1400DEG C, the plate blank is hot-rolled, and a hot-rolled plate is prepared; the hot-rolled plate is normalized; the hot-rolled plate after being normalized is cold-rolled, and a cold-rolled plate is obtained; the cold-rolled plate is decarburized and annealed, during decarburizing and annealing, the carbon content in the cold-rolled plate is reduced to below 30ppm, meanwhile, a SiO2 oxide layer is formed on the surface of the cold-rolled plate, the oxygen adhering amount of the cold-rolled plate is controlled to be less than 500ppm, and the reduction time is controlled to be greater than 100 seconds; the decarburized and annealed cold-rolled plate is dried and annealed with magnesium oxide as an isolating agent; and the dried and annealed cold-rolled plate is heated to 1170-1250 DEG C at a preset heating rate for high temperature annealing.