The invention relates to a high-
smoke suppression and high-
oxygen index 
phenolic aldehyde fire-proof heat-preserving board and a preparation method thereof and belongs to the technical field of a building fire-proof material. The high-
smoke suppression and high-
oxygen index 
phenolic aldehyde fire-proof heat-preserving board comprises the following components in parts by 
mass: 100 parts of phenolic resin, 10 to 20 parts of 
expansive fire retardant, 5 to 10 parts of liquid 
fire retardant, 5 to 8 parts of 
coal ash, 1 to 2 parts of tiny 
silicon powder, 1 to 2 parts of 
magnesium hydroxide, 5 to 7 parts of 
foaming agent, 5 to 7 parts of foam stabilizer and 20 to 30 parts of curing agent. The preparation method of the high-
smoke suppression and high-
oxygen index 
phenolic aldehyde fire-proof heat-preserving board comprises the following steps of 1) preparing a mixed 
slurry, i.e. (1) optionally selecting a formula, (2) mixing the phenolic resin and the liquid 
fire retardant, (3) mixing the 
expansive fire retardant, the hollow 
coal ash, the 
magnesium hydroxide and the tiny 
silicon powder, and adding the mixture into the mixed liquid, (4) adding the 
foaming agent and the foam stabilizer, and uniformly stirring the materials, and (5) adding the curing agent, stirring the materials, and filling the mixture into a die; and 2) molding and curing to obtain the fire-proof heat-preserving board. The fire-proof heat-preserving board has the advantages of convenience in construction, good 
fire resistance, low water absorption per volume, capability of meeting the requirements of high smoke suppression and 
high oxygen index of inner and outer wall heat-preserving boards, and the like.