The present invention provides an order-batch-mode limestone mortar wet desulphurization process, in particular relates to a high-efficient limestone desulphurization process that adopts the limestone mortar as the desulphurization agent, and adopts the order-batch alternative absorption reaction, and adopts the high-efficient desulphurization tower as the desulphurization device, and adopts lower pH value, lower liquid-gas ratio and economical desulphurization rate, and adopts the desulphurization waste slag as the byproduct. Smoke enters into the high-efficient desulphurization device, and a group of limestone mortar is adopted as absorption agent for the smoke to be desulphurized, until the pH value is decreased to a pre-determined value, and the smoke is temporarily withdrawn and the absorption is stopped; the absorption solution is continued to be reacted with the tiny particle of CaCO3, until the pH value is returned to the original value, and then another group of limestone mortar is filled to be desulphurized until the pH decreases to the pre-determined value; the mortar is filled at one group by another group for alternative absorption and after the mortar is reacted with the CaCO3, a new group of limestone mortar is replaced; the waste mortar is discharged after being processed; the waste slag is processed after being dehydrated. The order-batch-mode limestone mortar wet desulphurization process saves the investment, and has low operation expense, and is simple to be operated and managed, and has wide application, and resolves the scale formation problem of the tower and pool.