The present invention relates to an ionic phosphorescent
metal complex, and a preparation method and application thereof. The structure of the complex is represented by a general formula (I) as shownin the specification. In the formula (I), R1 and R2 are the same or different, and are independently selected from
alkyl,
aryl and heteroaryl groups; the
alkyl,
aryl and heteroaryl groups are optionally substituted by the group consisting of
halogen, an
alkyl group, an
alkoxy group, an alkylthio group, an amino group, an alkylamino group, a dialkylamino group, an arylamino group, a diarylamino group, a halogenated alkyl group, a cyano group, a nitro group, an alkenyl group, an
aryl group and a heteroaryl group optionally substituted by 1 to 3 aryl groups; R3 is one optionally selected from thegroup consisting of
halogen, an alkyl group, a haloalkyl group, an
alkoxy group, an alkylthio group, an amino group, an alkylamino group, a dialkylamino group, a cyano group, a nitro group, an alkenyl group and the like; and M is optionally selected from Cu (I), Ag (I) and Au (I). The invention further relates to an organic light-emitting
diode and a preparation method and application thereof. The organic light-emitting
diode prepared by taking the phosphorescent
metal complex as a light-emitting layer
dopant has high-performance
organic electroluminescence and can be applied to illuminationand panel display.