The invention discloses an intelligent hot-spot resistant photovoltaic assembly, and the assembly comprises an aluminum alloy frame, a first cover plate layer, a first package layer, a battery piece layer, a second package layer, a second cover plate layer, and a junction box. The battery piece layer is provided with a plurality of power optimization chips and a diode chip, and the battery piece layer comprises a plurality of battery strings. Each battery string is formed by the series connection of a plurality of battery pieces welded through a plurality of solder strips, and the battery strings are connected with each other through convergence strips. A power optimization chip is in parallel connection with the battery strings, and the diode chip is in reverse parallel connection with the battery pieces. The diode chip is in reverse parallel connection with each battery piece, thereby completely eliminating the hot-spot effect which may happen to the assembly, and improving the reliability of the assembly. The power optimization chip is connected with each battery string, thereby eliminating the mismatching between the battery strings, and enabling the power output of the batterystrings and the overall power output of the assembly to be maximized.