The invention belongs to the technical field of solar cells, and particularly relates to a
hybrid solar cell based on a CdS / CuInS2 /
polymer composite
heterojunction, a preparation method and application. The preparation method comprises the following steps: S1, mixing tetrabutyl
titanate,
ethanol and
acetic acid, spin-
coating to form a film, moisturizing after spin-
coating, and calcining to obtain a TiO2 nano-particle film; s2, InCl3. 4H2O, CuI and
thiourea are added into N, N-
dimethylformamide, and a precursor solution is obtained; dropwise adding the precursor solution onto the TiO2
nanoparticle film, and spin-
coating to obtain a precursor film; performing
drying, heat treatment and cooling to obtain a binary
heterojunction film; s3, adding MEH-PPV into
chlorobenzene, and stirring to obtain an MEH-PPV solution; preparing a P3HT solution and a PCE10 solution by adopting the same method; spin-coating the
polymer solution on the binary
heterojunction thin film to obtain a ternary heterojunction thin film; s4, diluting a PEDOT: PSS solution with isopropanol, then spin-coating the ternary heterojunction thin film with the diluted solution, and performing heat treatment to obtain a PEDOT: PSS thin film; and evaporating a gold
electrode on the PEDOT: PSS film, and sealing and assembling to obtain the
hybrid solar cell.