A
hybrid solar cell with
zinc oxysulfide serving as an
electron transfer layer is composed of a transparent conducting glass substrate, the
zinc oxysulfide
electron transfer layer, an inorganic
hybrid perovskite material, a 2,2',7,7'-tetrakis[N,N-di(4-nethoxyphenyl)amino]-9,9'-spirobifluorene
hole transport layer and an Au
metal back
electrode layer, wherein the
zinc oxysulfide
electron transfer layer, the inorganic
hybrid perovskite material, the 2,2',7,7'-tetrakis[N,N-di(4-nethoxyphenyl)amino]-9,9'-spirobifluorene
hole transport layer and the Au
metal back
electrode layer are sequentially combined to form a laminated structure, the inorganic hybrid
perovskite material is CH3NH3PbX3, and X is Cl or Br or I. The
hybrid solar cell and a preparation method have the advantages that the
hybrid solar cell has the large specific surface area and the good
electron transfer capacity when the zinc oxysulfide serves as the
electron transfer layer, electron-hole combination is effectively restrained, the
photoelectric conversion efficiency is high, and the preparation method is simple in process, low in
reaction temperature, high in efficiency, abundant in raw materials, low in cost, green, free of
pollution, and suitable of industrial large-scale production.