This invention provides a Cr2Se3
single crystal and its preparation method, relating to the field of
crystal materials technology. The Cr2Se3
single crystal preparation method, from
raw material proportioning and
powder preparation to
single crystal growth, involves coordinated steps to suppress
impurity introduction and
impurity phase formation, while simultaneously promoting ordered atomic arrangement and eliminating lattice vacancies and dislocations, resulting in a Cr2Se3 single
crystal with good single-phase properties, high
crystallinity, and extremely low defect density. The high-purity, low-defect single
crystal structure ensures its
semiconductor transport properties and antiferromagnetic order; it also eliminates interference from
impurity scattering and lattice
distortion, optimizing the
magnetic field's control over the magnetic moments of Cr atoms, enabling the single crystal to exhibit a strong CMR effect approaching -100%. Furthermore, the coordinated steps ensure consistency in size,
phase composition, and
structural integrity of the prepared Cr2Se3 single crystal, significantly improving the success rate, process
controllability, and
repeatability.