The invention discloses a zero-
discharge treating
system and a zero-
discharge treating method for industrial high-
salinity wastewater with abundant
refractory organics. The zero-
discharge treating
system comprises a
wastewater pond, a filtering pretreatment mechanism, an
electrodialysis concentrating and separating mechanism, a
desalination liquid pond, an advanced oxidation mechanism, a
reverse osmosis membrane concentration mechanism and a
nanofiltration membrane concentration mechanism which are communicated successively, the
electrodialysis concentrating and separating mechanism is connected with a concentrated liquid pond, the concentrated liquid pond is communicated with a crystalizing and salt producing mechanism, and a water outlet end of the
nanofiltration membrane concentration mechanism is connected to the filtering pretreatment mechanism and a concentrated liquid pond with the
refractory organics. The zero-discharge treating method and a process
route have the advantages that in a process of treating the industrial high-
salinity wastewater with the abundant
refractory organics, blockage problem of the organics can be alleviated, a
chemical cleaning period can be prolonged, service lives of membranes can be prolonged, normal operation of a salt distribution and
crystallization system is guaranteed, purities of
sodium sulfate crystal salt and
sodium chloride crystal salt are guaranteed, the amount of mother liquid discharge is decreased, operation cost of the integral zero-discharge treating system is reduced, and increasement of
investment cost on the system is not significant.