The invention relates to a zero-
discharge system and technology of desulphurization waste
water based on an
ion selective
electrodialysis technology. According to the
system, a
softening pretreatment mechanism comprises a reaction groove, a
clarifier and a filter device, and a reduction concentration mechanism is an ED
ion membrane device.
Fresh water precipitated by the ED
ion membrane device is reused as make-up water for a desulfurization
system, or is reused through the concentration of a
reverse osmosis membrane,
reverse osmosis membrane concentrated water returns to the process before
softening pretreatment, and circulation treatment is conducted. According to the zero-
discharge system and technology, through the treatment of a three-linkage-box technology,
lime is adopted and the pH of the
lime is adjusted to 9-9.5, no alkali needs to be added to adjust the pH to 11 or above, the addition amount of the
lime is small, few
calcium ions are carried in, the
calcium ions can generate precipitated
sodium carbonate or
sodium sulfate without adding more
calcium ions, and after clarification and
precipitation, filtered water directly enters the ED ion membrane device to be reduced and concentrated. Compared with the prior art, the technology processes are short, the operation and
investment cost is low, the system is convenient to maintain, the ion selective
electrodialysis technology is adopted, and the system has the advantages of being long in service life, low in requirement for
water quality, high in concentration multiple, low in operation load and little in
energy consumption.