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35results about How to "Improved photocorrosion resistance" patented technology

Ni doping Cd*.Zn*.*S micrometre ball photocatalyst and preparation method

The invention discloses Ni-doped Cd0.1Zn0.9 S microsphere photocatalyst and the preparation method thereof, the particle shape of the produced photocatalyst is a microsphere formed by nanometer crystals, and the doping amount of Ni is 0.1 percent to 0.5 percent of the weight of the catalyst. The invention has the preparation method that zinc sulfate, cadmium sulfate, nickel nitrate, and thioacetamide are taken as raw materials to form mixed solution which is sealed in a hydrothermal caldron and then laid in a baking oven to be insulated, naturally cooled to the room temperature, a resultant is obtained through cleaning, drying, and grinding. The Ni-doped Cd0.1Zn0.9S microsphere photocatalyst is prepared by the invention, and the anti-surface oxidation capability in air and the photo-corrosion resistant capability in the photocatalytic reaction are evenly enhanced greatly. Because the particle of the photocatalyst is microsphere-shaped, the photocatalytic activity for photocatalytic water splitting into hydrogen of visible light of the catalyst is greatly enhanced, and the highest hydrogen production rate reaches 191.01 micromole / (g*h). The quantum efficiency reaches 6.77 percent at the 420 nm position. After Pt of 0.6 wt percent is loaded, the highest hydrogen production rate reaches 585.45 micromole / (g*h), which is three times than the hydrogen production rate when the Pt is not loaded. The quantum efficiency reaches 15.9 percent at the 420 nm position, the activity is high, and the stability is good.
Owner:XI AN JIAOTONG UNIV

Photocatalytic composite material as well as preparation method and application thereof

The invention provides a preparation method of a photocatalytic composite material, and relates to the technical field of catalysts. The preparation method comprises the following steps: (1) carryingout soaking pretreatment on plant leaves, thus obtaining template biomass; (2) mixing a molybdenum source-sulfur source water solution with the template biomass obtained in step (1), and immersing, thus obtaining a composite material precursor; (3) calcining the composite material precursor obtained in step (2), thus obtaining the photocatalytic composite material. The photocatalytic composite material is prepared from needle-like molybdenum sulfide and biomass carbon, wherein the needle-like molybdenum sulfide is loaded on the surface of the flaky biomass carbon; the content of the biomass carbon is 70 to 90 percent, and the content of the molybdenum sulfide is 10 to 30 percent. The photocatalytic hydrogen production performance of the photocatalytic composite material prepared by the invention is superior to that of a pure molybdenum sulfide material, excellent photocorrosion resistance is obtained, and the hydrogen production efficiency is just reduced by about 10 percent after circulating for thrice.
Owner:SUZHOU UNIV OF SCI & TECH

Photoelectrocatalytic system and method for directionally converting degraded organic pollutants into synthesis gas

InactiveCN110240222AIncrease the number of refractionsUse helpWater/sewage treatment by irradiationWater treatment compoundsCathodic reactionIon exchange
The invention relates to a photoelectrocatalytic system and a method for directionally converting organic pollutants, degraded by using the photoelectrocatalytic system, into synthesis gas. The system is a single-chamber and two-pole system, wherein an anode material is Pd quantum dots (QDs)-TiO2 nanotubes (NTs), and a cathode material is Pd-Cu. Pd QDs are evenly deposited on the surface of a TiO2 NT electrode as an anode, and a copper mesh is modified by Pd by using an ion exchange method so as to form a cathode; the method can be used for directionally converting the organic pollutants, degraded by using the single-chamber and two-pole system in a way of high efficiency photoelectrocatalysis, into the synthesis gas. Compared with the prior art, the simple and convenient method realizes the directional conversion of the degraded organic pollutants into the synthesis gas, thus not only effectively degrading the pollutants and protecting the environment, but also converting the degraded products into the synthesis gas by means of a cathodic reaction and further fully utilizing the resources; the two purposes of pollutant degradation and resource recycling are realized by using one system; furthermore, carbon emission is reduced, so that the greenhouse effect is relieved.
Owner:TONGJI UNIV

Method for preparing Ag3PO4/GO/HAP composite photocatalyst by utilizing bovine bones

The invention discloses a method for preparing an Ag3PO4/GO/HAP composite photocatalyst by utilizing bovine bones, graphene oxide and silver nitrate, and belongs to the field of high-value resource utilization of animal husbandry solid wastes, and phosphate in the bovine bones is used as a phosphorus source of a silver phosphate photocatalyst. The preparation method comprises the following steps:crushing bovine bones into small blocks, boiling the small blocks with deionized water for several hours, washing the small blocks for several times until grease and collagen are removed, then puttingthe small blocks into a muffle furnace for pyrolysis to prepare biomass hydroxyl calcium phosphate, carrying out ball milling on the biomass hydroxyl calcium phosphate, and carrying out reaction in darkon the milled biomass hydroxyl calcium phosphate and a silver nitrate solution in which graphene oxide is dispersed under an ultrasonic condition, and then, carrying out washing, centrifuging and drying in vacuum to obtain the Ag3PO4/GO/HAP composite photocatalyst. The biomass hydroxyl calcium phosphate is prepared from the bovine bones which are wide in source and low in price, and the prepared catalyst product is high in photocatalytic activity in a visible light region and good in photocatalytic stability and photocorrosion resistance, can be used for degrading organic pollutants in industrial, agricultural and domestic discharged wastewater, and has good economic benefits and environmental benefits.
Owner:LANZHOU UNIVERSITY

Novel zinc ferrite and nickel doped zinc-indium-sulfur heterojunction photoelectrocatalytic anode material and preparation method thereof

The invention discloses a novel zinc ferrite and nickel doped zinc-indium-sulfur heterojunction photoelectrocatalysis anode material and a preparation method thereof. The zinc ferrite and nickel doped zinc-indium-sulfur heterojunction photoelectric catalyst material is prepared through an accurate and ordered three-time hydrothermal and dispensing experiment method. The preparation method of the heterojunction comprises the following steps: firstly, mixing deionized water, ferric chloride and sodium nitrate, and carrying out primary hydrothermal treatment to prepare iron oxyhydroxide; then, dispensing a zinc nitrate solution dissolved by a quantitatively proportioned solvent on a substrate, and carrying out drying, sintering and sodium hydroxide soaking to obtain a zinc ferrite substrate; then, mixing zinc chloride, indium chloride, thiourea and nickel chloride, and carrying out second-time hydrothermal preparation of a nickel-doped zinc-indium-sulfur film; and finally, a ferrocobalt passivation layer is loaded through a third hydrothermal method. Compared with common zinc ferrite, the zinc ferrite heterojunction prepared by the method has the remarkable advantages of excellent performance, excellent light corrosion resistance, stable performance and the like.
Owner:OCEAN UNIV OF CHINA

ABS alloy material capable of solving photocorrosion of plastic part, and preparation method of ABS alloy material

ActiveCN106366552AReduce etch intensityElimination of etched material phenomenaMicro nanoDisplay design
The invention discloses an ABS alloy material capable of solving photocorrosion of a plastic part, and a preparation method of the ABS alloy material. The preparation method comprises the following steps: mixing micro-nano semiconductor power and ABS resin, mixing other materials except for a light blocking agent uniformly, adding the mixture into an extrusion machine, adding the light blocking agent in a side feeding mode, melting, extruding, cooling, air-drying and dicing to obtain the ABS alloy material capable of solving the photocorrosion of the plastic part. The preparation method provided by the invention is simple, the prepared ABS alloy material can realize ultrahigh definition and transparency, the route of the transparency of a plastic hidden display part is overturned, and the problem that the definition and the transparency of the plastic hidden display part are mutually contradicted is solved successfully; meanwhile, the photocorrosion phenomenon of the plastic part is solved fundamentally and the fact that any print does not exist on the long-term illumination surface is guaranteed. Due to the excellent photocorrosion resistance of the product, the photocorrosion phenomenon which perplexes the household appliance industry for more than ten years is solved and the hidden display design of the household appliance industry is not limited any more.
Owner:ORINKO NEW MATERIAL CO LTD

A kind of ag prepared by using bovine bone 3 po 4 /go/hap composite photocatalyst method

The invention discloses a method for preparing Ag by using bovine bone, graphene oxide and silver nitrate 3 PO 4 The method of / GO / HAP composite photocatalyst uses phosphate in bovine bone as the phosphorus source of silver phosphate photocatalyst, which belongs to the field of high-value resource utilization of animal husbandry solid waste. It includes the following steps: breaking the bovine bone into small pieces, boiling it with deionized water for several hours and washing it several times until the grease and collagen are removed, and then putting it into a muffle furnace to pyrolyze it to obtain biomass calcium hydroxyphosphate, which is After ball milling, react with silver nitrate solution dispersed with graphene oxide in the dark under ultrasonic conditions, then wash, centrifuge, and vacuum dry to prepare Ag 3 PO 4 / GO / HAP composite photocatalyst. Biomass calcium hydroxyphosphate is made from bovine bone with a wide range of sources and low price. The prepared catalyst product has high photocatalytic activity in the visible light region, good photocatalytic stability and photocorrosion resistance, and can be used for degradation in industry, agriculture and life. The discharge of organic pollutants in wastewater has good economic and environmental benefits.
Owner:LANZHOU UNIVERSITY

Carbon-doped titanium dioxide polarized homojunction photoelectrocatalysis anode material and preparation method thereof

The invention discloses a carbon-doped titanium dioxide polarized homojunction photoelectrocatalysis anode material and a preparation method thereof. The homojunction takes conductive glass as a substrate, a layer of carbon-doped titanium dioxide film material is formed by regulating and controlling the pH value through a simple hydrothermal method, and then the homojunction titanium dioxide photoelectric catalytic material is formed by regulating and controlling the pH value and polarizing an ethanol solution. The preparation method of the homojunction comprises the following steps: firstly, mixing deionized water, hydrochloric acid and titanium isopropylate, doping quantitative carbon, and uniformly stirring; then, carrying out hydrothermal reaction, and carrying out high-temperature sintering; and finally, carrying out polarization treatment on the prepared titanium dioxide sample by using ethanol and water, and carrying out aging treatment. Compared with common titanium dioxide, the photoelectric anode subjected to polarization and aging treatment has the remarkable advantages of being excellent in performance, excellent in light corrosion resistance, stable in performance and the like.
Owner:OCEAN UNIV OF CHINA

Ni doping Cd0.1Zn0.9S micrometre ball photocatalyst and preparation method

The invention discloses Ni-doped Cd0.1Zn0.9 S microsphere photocatalyst and the preparation method thereof, the particle shape of the produced photocatalyst is a microsphere formed by nanometer crystals, and the doping amount of Ni is 0.1 percent to 0.5 percent of the weight of the catalyst. The invention has the preparation method that zinc sulfate, cadmium sulfate, nickel nitrate, and thioacetamide are taken as raw materials to form mixed solution which is sealed in a hydrothermal caldron and then laid in a baking oven to be insulated, naturally cooled to the room temperature, a resultant is obtained through cleaning, drying, and grinding. The Ni-doped Cd0.1Zn0.9S microsphere photocatalyst is prepared by the invention, and the anti-surface oxidation capability in air and the photo-corrosion resistant capability in the photocatalytic reaction are evenly enhanced greatly. Because the particle of the photocatalyst is microsphere-shaped, the photocatalytic activity for photocatalytic water splitting into hydrogen of visible light of the catalyst is greatly enhanced, and the highest hydrogen production rate reaches 191.01 micromole / (g*h). The quantum efficiency reaches 6.77 percent at the 420 nm position. After Pt of 0.6 wt percent is loaded, the highest hydrogen production rate reaches 585.45 micromole / (g*h), which is three times than the hydrogen production rate when the Pt is not loaded. The quantum efficiency reaches 15.9 percent at the 420 nm position, the activity is high, and the stability is good.
Owner:XI AN JIAOTONG UNIV

A kind of photocatalytic composite material and its preparation method and application

The invention provides a preparation method of a photocatalytic composite material, and relates to the technical field of catalysts. The preparation method comprises the following steps: (1) carryingout soaking pretreatment on plant leaves, thus obtaining template biomass; (2) mixing a molybdenum source-sulfur source water solution with the template biomass obtained in step (1), and immersing, thus obtaining a composite material precursor; (3) calcining the composite material precursor obtained in step (2), thus obtaining the photocatalytic composite material. The photocatalytic composite material is prepared from needle-like molybdenum sulfide and biomass carbon, wherein the needle-like molybdenum sulfide is loaded on the surface of the flaky biomass carbon; the content of the biomass carbon is 70 to 90 percent, and the content of the molybdenum sulfide is 10 to 30 percent. The photocatalytic hydrogen production performance of the photocatalytic composite material prepared by the invention is superior to that of a pure molybdenum sulfide material, excellent photocorrosion resistance is obtained, and the hydrogen production efficiency is just reduced by about 10 percent after circulating for thrice.
Owner:SUZHOU UNIV OF SCI & TECH
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