The invention discloses an
alkali metal charge compensation type Mn<4+> activated aluminophosphate
luminescent material as well as a preparation method and application thereof, and belongs to the technical field of luminescent materials. The
chemical composition is CaAl<11.9-x-y>P0.1O19.1: xMn < 4 + >, yR < + >, wherein R is Li, Na, K, Rb or Cs < + >, x is greater than or equal to 0.001 and less than or equal to 0.15, and y is greater than or equal to 0 and less than or equal to 1.0. According to the invention,
aluminate,
phosphate and
calcium salt are used as raw materials,
lithium salt,
sodium salt,
potassium salt,
rubidium salt and cesium salt are used as
charge compensation agents,
manganese salt is used as an activating agent, and an improved high-temperature
solid phase method is adopted to prepare the material. The preparation method is easy in
raw material obtaining, simple in process, convenient to operate, low in cost and
environmentally friendly, and the prepared sample is excellent in
luminescence property, long in
fluorescence lifetime, high in
color purity and good in stability. The aluminophosphate
luminescent material can be widely applied to lighting and display devices and
plant growth light-emitting diodes, and is a promising red
luminescent material.