The invention discloses a preparation method of superfine
glass fiber, and the method comprises the following steps: S1, soaking glass fibers in a
sodium hydroxide aqueous solution, washing,
drying, uniformly dispersing in an
organic solvent to obtain a solution A, adding diisocyanate and a catalyst, reacting, filtering, and washing a
filter cake to obtain an intermediate material; and S2, uniformly dispersing the intermediate material in an
organic solvent to obtain a solution B, adding
diamine into the solution B in an
inert gas
atmosphere for reaction, filtering, washing a
filter cake, anddrying to obtain the superfine
glass fiber. The invention further discloses the superfine
glass fiber which is prepared according to the preparation method of the superfine glass
fiber. The inventionalso discloses application of the ultrafine glass
fiber in a
polyimide film. The invention further discloses a low-heat-shrinkage
polyimide film. The surface of the prepared superfine glass
fiber is grafted with-NH2, and the superfine glass fiber can be combined with
polyimide to achieve the effects of reducing
thermal shrinkage of the polyimide film and maintaining mechanical properties.