The invention relates to a nanometer polyvinyl chloride pipe and a preparation method thereof. According to weight ratio, raw materials of the nanometer polyvinyl chloride pipe comprise nanometer polyvinyl chloride resin, calcium carbonate, and PME-100 strengthening and toughening agent, etc. The preparation method is that: first, the raw materials needed are fully mixed in a high level mixing pot and a low level mixing pot; then the materials mixed are transported to an extruder production line to do extruding molding, thereby gaining the nanometer polyvinyl chloride pipe. The invention is characterized in that the invention is not only environment-friendly, but also solves the problems of insufficiency of thermal stability, initial coloring and products reddened and zinc burned, bad weather resistance and copper erosion, etc. During the mixing process of the preparation method, the plasticizing time is shortened, leading to a good plasticizing uniformity and being in favor of the basic extrusion molding process to the modification polyvinyl chloride. The mechanical property of the invention is distinctively higher than the common polyvinyl chloride resin and nanometer blending composite resin. The anti-impact performance and other performances are greatly enhanced The shock strength is two times the common resin products, and in particular the products has good shock strength in low temperature; in addition, the invention has good bending performance, thus being applied to no digging laying and repairing, etc.