The invention belongs to the technical field of glaze preparation, and particularly relates to secret-color porcelain glaze which is prepared from the following raw materials in parts by weight: 45-60parts of potassium feldspar, 12-20 parts of quartz, 7-15 parts of fluorite, 12-20 parts of plant ash, 1-3 parts of titanium oxide, 1-3 parts of ferric oxide, 1-3 parts of gold ore and 1-3 parts of marble. The invention also discloses a preparation method of the secret-color porcelain glaze. The preparation method comprises the following steps: (1) weighing the raw materials according to the proportion,(2) fully crushing the raw materials, and uniformly mixing to obtain a mixed glaze material, (3) adding the mixed glaze into a ball mill, and adding water for ball milling to obtain glaze slip,(4) uniformly applying the glaze slip to a biscuiting blank, drying the glazed blank, putting the dried glazed blank into a kiln for firing, heating to 1260-1300 DEG C in an oxidizing atmosphere in astepped heating manner, keeping the temperature for 60-80 minutes, and naturally cooling to room temperature, thereby obtaining the secret-color ceramic glaze. The secret-color porcelain prepared by the raw material ratio and the preparation method disclosed by the invention is good in coloring effect, uniform in glaze color, high in glossiness, high in hardness, free of cracks and high in yield.