The invention provides a high calorific value environment-friendly alcohol-based fuel, which is prepared from the following raw materials by weight: 40-70 parts of alcohol-based fuel; 10-20 parts of anovel calixarene combustion improver; 0.5-4.5 parts of a cosolvent; 2-7 parts of an oxygen producer; 1-5 parts of a stabilizer; 0.1-0.5 part of Tween; and 1-2 parts of triethanolamine. The novel calixarene combustion improver is prepared according to the method of: in a four-mouth bottle equipped with a stirrer, a nitrogen protection device, a thermometer and a water segregator, adding p-methoxyphenol, paraformaldehyde, a sodium hydroxide solution, naphthalene and a solvent xylene, introducing nitrogen for protection, conducting oil bath heating to reflux, carrying out reaction for 4h, performing cooling to room temperature, conducting filtering, and washing the filter cake with toluene, petroleum ether, acetone and water respectively in order, performing drying, then performing dissolving in chloroform, conducting heating concentration, carrying out cooling to room temperature, and performing filtering to obtain yellow powder. Compared with refined methanol fuel or ethanol fuel, thehigh calorific value environment-friendly alcohol-based fuel prepared according to the invention has wide source, low cost, and higher calorific value, does not generate toxic gas during combustion, and is economical and environment-friendly.