The application discloses a kind of
solid supported
copper-based N-heterocyclic
carbene catalytic materials and preparation method and application thereof, and it is related to
material synthesis technical field.The preparation method of the catalytic material includes: cuprous
oxide is reacted with N-heterocyclic
carbene ligand containing
bromine group in
solvent, and
copper-based N-heterocyclic
carbene complex is formed;The complex is subjected to
Sonogashira coupling reaction with
alkyne compound under the action of catalyst, and
bromine group on the complex is coupled with
alkyne compound and occurs copolymerization, forms porous
organic polymer skeleton, and
copper-based N-heterocyclic carbene complex is distributed in the skeleton, and
solid supported copper-based catalytic material is obtained;Wherein
alkyne compound is selected from 1,3,5-triethynylbenzene or 1,3,5-tri (4-ethynylphenyl)
benzene.The obtained catalytic material has porous
organic polymer skeleton, and copper active species is uniformly distributed in the whole material, belongs to heterogeneous catalytic material, is easy to separate and recycle, can be recycled, and shows excellent catalytic performance in alkyne
alkylation reaction of
trifluoromethyl ketone.