The invention discloses a preparation method of modified activated carbon fiber filaments loaded with nano-titanium dioxide on the surface, belongs to the field of photocatalytic materials in environmental protection, and has wide application in the fields of water purification, waste water treatment, waste gas treatment, air purification, disinfection and antibacterial, etc. research and application prospects. In the present invention, the modified activated carbon fibers are fully immersed in a mixed solution formed by nano-TiO2 (Degussa P25), acetone, epoxy resin, UV‑P and nano-Fe2O3, and then dried under a nitrogen atmosphere. The modified activated carbon fiber filaments with nano-titanium dioxide loaded on the surface can be obtained. The various raw materials used in the present invention are easy to obtain, the preparation method is simple, the nano-TiO2 layer has the advantages of high cohesion, good stability, uniform loading, wide excitation light wavelength range, and good photocatalytic performance; it can be widely used in the purification of water , waste water treatment, waste gas treatment, air purification, disinfection and antibacterial and other fields.