The invention discloses high-refractive-index watch glass for a watch outer cover and a production process of the high-refractive-index watch glass. The high-refractive-index watch glass is prepared from silicon dioxide, aluminum oxide, borax, calcium carbonate, zinc oxide, dolomite, sodium carbonate, a clarifying agent and an initiator. The mass percentage of each component is as follows: 20-30%of silicon dioxide, 15-25% of aluminum oxide, 15-25% of borax, 10-20% of calcium carbonate, 2-4% of zinc oxide, 10-20% of dolomite, 1-3% of sodium carbonate, 5-10% of a clarifying agent and 2-5% of aninitiator. The glass is safe and reliable, silicon dioxide, aluminum oxide, borax, calcium carbonate, zinc oxide and dolomite are adopted as raw materials and subjected to dissolving processing and then compression molding, the glass crystallization phenomenon is reduced, the stability and strength of the watch glass are improved, the glass absorbs short-wavelength rays, the refractive index anddispersion of the watch glass are improved, the process is simple and rigorous, the raw materials are cheap, and the cost is low; machining is convenient, the production cost is greatly saved, and machining and production are facilitated.