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44results about How to "Reduce devitrification" patented technology

Preparation method of wet-process high-strength polyacrylonitrile-based carbon fiber

The invention relates to a preparation method of a wet-process high-strength polyacrylonitrile-based carbon fiber. The preparation method sequentially comprises the following steps: step1. preparing a PAN (Polyacrylonitrile) copolymer; step 2. removing monomers and removing foams; step 3. filtering and metering; step 4. carrying out consolidation forming; step 5. carrying out primary-drafting, washing, drying and compacting, re-drafting and thermally setting to prepare precursor fibers; and step 6. carrying out pre-oxidizing, low-temperature carbonizing and high-temperature carbonizing to finally obtain carbon fibers, wherein the coagulating bath system used in the step 4 consists of a good solvent of polyacrylonitrile, precipitator water and water soluble low carbon fatty amine. According to the preparation method provided by the invention, contact between the polymer and the precipitator water is alleviated by means of the appetency of the low carbon fatty amine and the polymer component to accelerate the solution trickle to precipitate with a slow speed phase so as to effectively reduce hole defects and skin cores of the precursor fibers in the conventional wet-process solidification forming process, so that the shape structure of the precursor fibers is improved, devitrification and non-uniformity of the precursor fibers are reduced, radial solidification and dispersion uniformity of the solution trickle are expanded and strands far from the bath are compact and transparent.
Owner:BEIJING UNIV OF CHEM TECH +1

Glass microballoon manufacturing device and preparation method thereof

The invention discloses a glass microballoon manufacturing device comprising a furnace body (1) and a waste gas treatment device, wherein the furnace body (1) is formed by air-tight connection of an upper part and a lower part, the upper part of the furnace body is of a cubic shape, a waste gas emission port (4) is arranged at the top of the upper part, one or more injection-type burners (2) are horizontally installed on the side of the upper part, a preheating air pipe (14) is arranged in the upper part, the lower part of the furnace body is of a square conical shape, and one or more microballoon collectors (3) are arranged at the bottom of the lower part. According to the glass microballoon manufacturing device and the preparation method thereof provided by the invention, the furnace body which adopts the cubic structure enlarges the cooling space; the horizontally installed injection-type burners and the preheating air pipe arranged in the furnace body can give full play to the heat value of fuel, thus reducing energy source waste, saving energy and reducing emission; TiO2 and Al2O3 with relatively lower costs are adopted, the refractive index of the product is greater than or equal to 1.93; and the glass microballoon manufacturing device and the preparation method thereof have the advantages of reducing devitrification, improving the cooling velocity, having good product quality, improving the utilization ratio of raw material, being capable of large-scale production, and the like.
Owner:SICHUAN ZHONGKE BETTER TECH

Ultra-high strength and middle high-modulus polyacrylonitrile carbon fibers as well as preparation method thereof

The invention discloses an ultra-high strength and middle high-modulus polyacrylonitrile carbon fibers as well as preparation method thereof. The method comprises the following steps: (1) using dimethyl sulfoxide or dimethylformacetamide as a solvent, and performing copolymerization on acrylonitrile and itaconic acid or acrylonitrile, methyl acrylate and itaconic acid; (2) spinning, drafting, washing, oiling, drying, and heat setting a polymer spinning solution in sequence; (3) performing pre-oxidation and carbonization on polyacrylonitrile strand to obtain ultra-high strength, middle high-modulus carbon fiber. The components of the coagulation bath system in a spinning process cannot penetrate into a spinning stream formed by the polymer spinning solution, and the solvent in the spinningstream formed by the polymer spinning solution can diffuse into the coagulation bath system.According to the method provided by the invention, a raw wire hole defect and a skin and core structure inhomogeneity defect formed by a traditional wet or dry-wet solidification molding process can be reduced; highly oriented raw silkstrand can be easily obtain from a fiber initial structure; the raw silkstrand is used to obtain carbon fiber with tensile strength of 5,500-7,000 MPa and tensile modulus 310-390 GPa.
Owner:BEIJING UNIV OF CHEM TECH

Low-dielectric sealing glass granulation powder and preparation method thereof

The invention discloses a low dielectric sealing glass granulation powder and a preparation method thereof, the sealing glass comprises the following components by mole percentage based on oxide: 68.2% to 72.3% of SiO2, 20.7% to 24.8% of B2O3, 1% to 2% of Al2O3, 2% to 3% of Na2O, 0.5% to 1% of K2O, 0.5% to 1% of CaO, and 0.5% to 1% of Bi2O3. The preparation method comprises the following steps: uniformly mixing the raw materials corresponding to the components, melting at 1600-1650 DEG C, quenching to obtain glass slag, carrying out ball milling on the glass slag, pulping, and carrying out spray granulation to obtain granulation powder with certain particle size and sphericity. And preparing the granulated powder into a glass blank with a required shape by compression molding, and placing the glass blank at a certain temperature for glue removal and vitrification to obtain the prefabricated glass bead for sealing. The sealing glass prepared by the method is relatively low in high-temperature viscosity after being melted, and glass residues are easy to recover; and meanwhile, the granulation powder has better sphericity and flowability, and the formed glass blank is transparent and white after glue removal and vitrification. Meanwhile, the dielectric constant and dielectric loss of the sealing glass are small, the dielectric constant is 3.9-4.2 under the frequency of 1 MHz, the dielectric loss is 1 * 10 <-3 >-4 * 10 <-3 >, and the sealing temperature is 840-900 DEG C.
Owner:XIAN SEAL ELECTRONICS MATERIAL TECH CO LTD

Glass microballoon manufacturing device and preparation method thereof

The invention discloses a glass microballoon manufacturing device comprising a furnace body (1) and a waste gas treatment device, wherein the furnace body (1) is formed by air-tight connection of an upper part and a lower part, the upper part of the furnace body is of a cubic shape, a waste gas emission port (4) is arranged at the top of the upper part, one or more injection-type burners (2) are horizontally installed on the side of the upper part, a preheating air pipe (14) is arranged in the upper part, the lower part of the furnace body is of a square conical shape, and one or more microballoon collectors (3) are arranged at the bottom of the lower part. According to the glass microballoon manufacturing device and the preparation method thereof provided by the invention, the furnace body which adopts the cubic structure enlarges the cooling space; the horizontally installed injection-type burners and the preheating air pipe arranged in the furnace body can give full play to the heat value of fuel, thus reducing energy source waste, saving energy and reducing emission; TiO2 and Al2O3 with relatively lower costs are adopted, the refractive index of the product is greater than or equal to 1.93; and the glass microballoon manufacturing device and the preparation method thereof have the advantages of reducing devitrification, improving the cooling velocity, having good product quality, improving the utilization ratio of raw material, being capable of large-scale production, and the like.
Owner:SICHUAN ZHONGKE BETTER TECH

High-refractive-index watch glass for watch outer cover and production process of high-refractive-index watch glass

The invention discloses high-refractive-index watch glass for a watch outer cover and a production process of the high-refractive-index watch glass. The high-refractive-index watch glass is prepared from silicon dioxide, aluminum oxide, borax, calcium carbonate, zinc oxide, dolomite, sodium carbonate, a clarifying agent and an initiator. The mass percentage of each component is as follows: 20-30%of silicon dioxide, 15-25% of aluminum oxide, 15-25% of borax, 10-20% of calcium carbonate, 2-4% of zinc oxide, 10-20% of dolomite, 1-3% of sodium carbonate, 5-10% of a clarifying agent and 2-5% of aninitiator. The glass is safe and reliable, silicon dioxide, aluminum oxide, borax, calcium carbonate, zinc oxide and dolomite are adopted as raw materials and subjected to dissolving processing and then compression molding, the glass crystallization phenomenon is reduced, the stability and strength of the watch glass are improved, the glass absorbs short-wavelength rays, the refractive index anddispersion of the watch glass are improved, the process is simple and rigorous, the raw materials are cheap, and the cost is low; machining is convenient, the production cost is greatly saved, and machining and production are facilitated.
Owner:DONGGUAN JINGSHI OPTICAL CO LTD
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