A method for preparing aromatic hydrocarbons with
carbon dioxide hydrogenation, comprising: directly converting a
mixed gas consisting of
carbon dioxide and
hydrogen with the
catalysis of a composite catalyst under
reaction conditions of a temperature of 250-450° C., a pressure of 0.01-10.0 MPa, a feedstock gas hourly
space velocity of 500-50000 mL / (h·gcat) and a H2 / CO2
molar ratio of 0.5-8.0, to produce aromatic hydrocarbons. The composite catalyst is a mixture of a first component and a second component. The first component is an iron-based catalyst for making low-carbon olefin via
carbon dioxide hydrogenation, and the second component is at least one of
metal modified or non-modified molecular sieves which are mainly used for olefin
aromatization. In the method, CO2 conversion per pass may be above 33%, the
hydrocarbon product selectivity may be controlled to be above 80%, the
methane content is lower than 8%, C5+
hydrocarbon content is higher than 65% and the proportion of the aromatic hydrocarbons in C5+ hydrocarbons may be above 63%.