The invention discloses a composite material for manufacturing a dry powder fire extinguisher spraying pipe, wherein the composite material comprises the following raw materials by mass: 80-100 partsof a mixture of silicone rubber and a CPVC resin, 25-40 parts of a plasticizer, 6-8 parts of a heat stabilizer, 6-10 parts of nitrile butadiene rubber, 12-16 parts of a hot melt adhesive, 2-4 parts ofa cross-linking agent, 7-10 parts of an accelerator, 3-8 parts of oxidized polyethylene wax, 0.3-0.6 part of an internal lubricant, 2-10 parts of flame retardant, 5-15 parts of modified calcium carbonate with an average particle size of less than or equal to 0.01 [mu]m, and 15-20 parts of carbon black, wherein a mass ratio of the silicone rubber to the CPVC resin is 1:4-1:6. The invention furtherprovides a method for manufacturing a dry powder fire extinguisher spraying pipe by using the composite material, wherein the spraying pipe integrates excellent elasticity, flexing resistance, high temperature resistance, aging resistance, flame retardancy and compressive resistance, and has high inner surface smoothness so as to greatly reduce the adhesion rate of dry powder on the inner wall.