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Method for smelting low-aluminum high-vanadium iron

The invention discloses a method for smelting low-aluminum high-vanadium iron. The method comprises the following steps of: 1, smelting by adopting an outside furnace process, mixing vanadium pentoxide, aluminum powder, scrap steel, vanadium iron slag or lime, igniting and reacting to generate high-vanadium iron and furnace slag; and 2, uniformly mixing vanadium pentoxide and lime at a reducing stage by adopting an electric furnace process, putting the mixture into an electric arc furnace, adding scrap steel, adding industrial silicon and ferro-silico aluminum depleted furnace slag after the material is in a molten state, deslagging when the vanadium content of the furnace slag is below 0.5 percent, extracting an alloy sample and analyzing vanadium and silicon for monitoring before deslagging, putting vanadium pentoxide and lime into the furnace at a refining stage, electrifying to refine and pouring with a ladle after qualification is determined. The method has the advantages that aluminothermic process smelting is integrated with electro-silicothermic process smelting, chemical reaction heat of vanadium pentoxide and aluminum is fully utilized, furnace slag with high vanadium content is depleted, reduced and refined in a three-phase electric arc furnace to obtain high-vanadium low-aluminum qualified high-vanadium iron, the vanadium content of discharged furnace slag is lower than 0.5 percent, and the smelting yield is over 95 percent.
Owner:锦州钒业有限责任公司

Method for preparing tungsten from WO3

The invention relates to a method for preparing tungsten from WO3, belonging to the technical field of electrolysis and electrophoresis. The method is used for realizing one-step electrodeposition to obtain WO3 from with fused salt as medium under the action of pulse direct current. The method is characterized in that a component comprising NaCl, KCl and NaWO4 is used as medium, wherein the molar ratio of NaCl to KCl to NaWO4 is 2:2:(0.01-2):2:0.05, and the powdered WO3 which is 10-20 wt% of the fused salt medium is added; and after impurity removal by pre-electrolysis, pure tungsten is obtained by electrodeposition at an electrodeposition temperature of 650-750 DEG C, electrodeposition time of 1-3 hours and current density of 300-600 A/m2. The method provided by the invention has the following characteristics: (1) the component of the fused salt is common cheap agent, is easily-accessible and has low cost and less consumption; (2) the production technology has short process and wide parameter control range, and is easy to operate and implement; (3) the electrodeposition temperature is low, so that the fused salt does not volatilize; and (4) the component of the fused salt can be ensured to not to change with the prolongation of the electrodeposition time, so as to ensure the stability of electrodeposition process. The method has good prospect in tungsten production and applications.
Owner:NORTH CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY
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