The invention belongs to the technical field of adsorbents, and discloses preparation of a magnetic
fluorine functionalized three-dimensional
covalent organic framework and application of the magnetic
fluorine functionalized three-dimensional
covalent organic framework in analysis of
benzoylurea insecticides, and the preparation method of the magnetic
fluorine functionalized three-dimensional
covalent organic framework comprises the following steps: mixing an
ammonia source,
anhydrous sodium acetate,
ferric chloride and
ethylene glycol according to a ratio, and stirring uniformly; heating, violently stirring and premixing, and then heating and reacting for set time to obtain NH2-Fe3O4; the preparation method comprises the following steps: mixing and
grinding tetra (4-aminophenyl)
methane, 2, 3, 5, 6-tetrafluoro-p-dibenzaldehyde, NH2-Fe3O4, 1-butyl-3-methylimidazolium bis (trifluoromethylsulfonyl)
imide and 1-carboxymethyl-3-methylimidazolium bis (trifluoromethylsulfonyl)
imide according to a ratio, introducing
nitrogen into a
reaction system, emptying air, sealing, and reacting at 20-40 DEG C for 10-30 hours, so as to obtain the
tetra (4-aminophenyl)
methane, 2, 3, 5, 6-tetrafluoro-p-dibenzaldehyde, NH2-Fe3O4, 1-butyl-3-methylimidazolium bis (trifluoromethylsulfonyl)
imide and 1-carboxymethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide. And after the reaction is finished, extracting by using an
organic solvent, and
drying an extracting solution to obtain the NH2-Fe3O4-coated F-3D COF. The NH2-Fe3O4 (at) F-3D COF shows strong adsorption performance on the
BUs through the interaction of fluorine-fluorine affinity and
hydrogen bonds.