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120 results about "Multi shell" patented technology

Vertical group iii-v nanowires on si, heterostructures, flexible arrays and fabrication

Embodiments of the invention provide a method for direct heteroepitaxial growth of vertical III-V semiconductor nanowires on a silicon substrate. The silicon substrate is etched to substantially completely remove native oxide. It is promptly placed in a reaction chamber. The substrate is heated and maintained at a growth temperature. Group III-V precursors are flowed for a growth time. Preferred embodiment vertical Group III-V nanowires on silicon have a core-shell structure, which provides a radial homojunction or heterojunction. A doped nanowire core is surrounded by a shell with complementary doping. Such can provide high optical absorption due to the long optical path in the axial direction of the vertical nanowires, while reducing considerably the distance over which carriers must diffuse before being collected in the radial direction. Alloy composition can also be varied. Radial and axial homojunctions and heterojunctions can be realized. Embodiments provide for flexible Group III-V nanowire structures. An array of Group III-V nanowire structures is embedded in polymer. A fabrication method forms the vertical nanowires on a substrate, e.g., a silicon substrate. Preferably, the nanowires are formed by the preferred methods for fabrication of Group III-V nanowires on silicon. Devices can be formed with core / shell and core / multi-shell nanowires and the devices are released from the substrate upon which the nanowires were formed to create a flexible structure that includes an array of vertical nanowires embedded in polymer.
Owner:RGT UNIV OF CALIFORNIA

Multi-shell-layer metal oxide hollow ball and preparation method thereof

The invention provides a multi-shell-layer metal oxide hollow ball and a preparation method thereof. A hydrothermal method is used for preparing a carbon ball template; metal salts are dissolved in carbon ball suspension liquid, and the gradient distribution, the depth and the number of metal salts entering carbon balls are controlled through regulating adsorption conditions such as metal salt concentration, solution pH value, soaking temperature and time and the like; and the heat treatment is carried out on the carbon balls adsorbing metal ions, and the multi-shell-layer metal oxide hollow ball can be obtained. The shell-layer of the hollow ball prepared by the method is formed by accumulating nanometer crystal particles of metal oxides, the shell layer number can be regulated and changed from two to four, and both the size of the hollow ball and the thickness of the shell layers are controllable. The method provided by the invention is simple and is easy to implement, the controllability is high, the pollution is little, the cost is low, and in addition, the general applicability is realized. The prepared product has a hollow structure and the shell layers with the thickness inthe nanometer level, simultaneously, the internal space can be effectively utilized through the multilayer structure, and the multi-shell-layer metal oxide hollow ball is applied to gas sensitivity and photocatalysis and has the more excellent performance through being compared with the traditional nanometer material and a single-layer hollow ball.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Cobaltosic oxide multi-shell hollow sphere cathode material for lithium ion battery and preparation method thereof

The invention provides a cobaltosic oxide multi-shell hollow sphere cathode material for a lithium ion battery and a preparation method thereof. The method comprises the steps of: taking a carbon sphere prepared by a hydrothermal method as a template; controlling the quantity of cobalt ions in the carbon sphere and the entering depth thereof by controlling the ratio of water to ethanol in a cobalt salt solution, the temperature of the solution and the adsorption capacity of the carbon sphere; and preparing single-shell, dual-shell, tri-shell and four-shell cobaltosic oxide hollow spheres. The lithium ion battery of taking the cobaltosic oxide multi-shell hollow sphere as a cathode has large specific surface area and a plurality of lithium ion storage sites; the specific capacitance is improved; meanwhile, the appropriate multi-shell cavity structure not only can adjust the electrode structure and volume change, but also can effectively reduce the transmission distance between the lithium ion and electrons. Thus, the cycling performance and rapid charge and discharge capacity are obviously improved. The method disclosed by the invention is convenient and concise to operate, and high in controllability, and has a wide application prospect; and the performance of the lithium ion battery can be obviously improved.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Combined heat exchange type multi-shell side methanol-to-olefin fixed bed production equipment and production method thereof

Belonging to the technical field of olefin production, the invention relates to combined heat exchange type multi-shell side methanol-to-olefin fixed bed production equipment and a production method thereof, thereby solving the technical problems of complex reaction equipment and difficult control of heat transfer in existing fixed bed reactors. The invention firstly puts forward the combined at exchange type multi-shell side methanol-to-olefin fixed bed production equipment, which includes a main reactor. Partition plates are mounted between an upper tube plate and a lower tube plate of the main reactor, and divide the cavity surrounded by the upper tube plate, the lower tube plate and the reactor body into 2-10 heat exchange shell sides that are not communicated to each other. The heat exchange shell sides include a first heat exchange shell side and the rest heat exchange shell sides, and column tubes run through the partition plates. The reactor body of each heat exchange shell side is provided with a cooling medium inlet and a cooling medium outlet. The invention also provides a method for production of olefin by the equipment. By means of combined high efficiency heat exchange, the proportion of water vapor in the feed gas and the load of a feed gas heating furnace can be reduced.
Owner:INNOVATIVE COAL CHEMICAL DESIGN INSTITUTE (SHANGHAI) CO LTD

Preparation method of yolk type double-shell-layer hollow composite wave absorption material

The invention provides a preparation method of a yolk type double-shell-layer hollow composite wave absorption material. A double-shell-layer hollow composite microsphere is used as a template; a transition layer covers the surface; the multi-shell-layer hollow composite microsphere is obtained; the multi-shell-layer hollow composite microsphere is used as a template; a dielectric layer with a dielectric loss function covers the surface; then, the transition layer is removed to obtain the yolk type double-shell-layer hollow composite wave absorption material. The prepared material is a composite wave absorption material with strong wave absorption, wide frequency band and light weight; the magnetic loss and the electric loss are integrated; the wave absorption performance of the compositematerial is enhanced; the wave absorption frequency band of the composite material is widened; in addition, the unique yolk hollow double-space structure is realized, so that the composite material has the lower density and lighter weight on the basis of maintaining the excellent wave absorption performance; the requirements of strong wave absorption, wide frequency band and light weight of the modern wave absorption material can be met.
Owner:SHAANXI UNIV OF SCI & TECH

Multi-hole-and-shell nickel phosphide hollow microsphere and preparation method and application thereof

A multi-hole-and-shell nickel phosphide hollow microsphere compound is provided with a multi-hole secondary nanostructure, and the chemical formula of the multi-hole-and-shell nickel phosphide hollow microsphere compound is Ni2P, wherein Ni to P is 2:1; the diameter of the microsphere is 1.5-2.5 [mu]m, and multi-hole shells are formed by assembling secondary nano particles being 12-17 nm; a solid phase phosphide multi-shell NiO precursor method is adopted for preparation of the multi-hole-and-shell nickel phosphide hollow microsphere compound, and a precursor NiO of the method is prepared through a self-template method; and a material can form a three-electrode system for testing of an electro-catalysis hydrogen evolution property of the material. The multi-hole-and-shell nickel phosphide hollow microsphere compound has the advantages that a multi-hole-and-shell hollow structure formed by assembling the nano particles is advantageous to interface contact of electrode gas-liquid-solid three phases, a better material conveying channel can be provided, and a structural unit of the nano particles can provide more catalytic active sites, so that electro-catalysis activity of the multi-hole-and-shell nickel phosphide hollow microsphere compound is effectively improved, and meanwhile, a product has good electrochemical stability and can serve as a novel catalyst to be applicable to electrolysed water and the like.
Owner:NANKAI UNIV

Vertical group III-V nanowires on si, heterostructures, flexible arrays and fabrication

Embodiments of the invention provide a method for direct heteroepitaxial growth of vertical III-V semiconductor nanowires on a silicon substrate. The silicon substrate is etched to substantially completely remove native oxide. It is promptly placed in a reaction chamber. The substrate is heated and maintained at a growth temperature. Group III-V precursors are flowed for a growth time. Preferred embodiment vertical Group III-V nanowires on silicon have a core-shell structure, which provides a radial homojunction or heterojunction. A doped nanowire core is surrounded by a shell with complementary doping. Such can provide high optical absorption due to the long optical path in the axial direction of the vertical nanowires, while reducing considerably the distance over which carriers must diffuse before being collected in the radial direction. Alloy composition can also be varied. Radial and axial homojunctions and heterojunctions can be realized. Embodiments provide for flexible Group III-V nanowire structures. An array of Group III-V nanowire structures is embedded in polymer. A fabrication method forms the vertical nanowires on a substrate, e.g., a silicon substrate. Preferably, the nanowires are formed by the preferred methods for fabrication of Group III-V nanowires on silicon. Devices can be formed with core / shell and core / multi-shell nanowires and the devices are released from the substrate upon which the nanowires were formed to create a flexible structure that includes an array of vertical nanowires embedded in polymer.
Owner:RGT UNIV OF CALIFORNIA

Single-particle nano crystal with three-primary-color luminescence and preparation method thereof

The invention provides a single-particle nano crystal with three-primary-color luminescence and a preparation method thereof. The single-particle nano crystal has a core-shell structure and sequentially comprises an inner core, a first shell, a second shell, a third shell and a fourth shell from inside to outside, wherein the inner core, the second shell and the fourth shell are luminous shells, and the first shell and the third shell are inert shells. The three luminous shells separately contain Yb<3+>/Tm<3+>, Er<3+> or Nd<3+>/Yb<3+>/Er<3+> ions, and the luminescent shells respectively radiate red, green and blue lights under the action of a laser. According to the invention, shell stock solutions with different components are continuously and thermally injected by adopting a one-pot method, and compared with a conventional batch thermal injection method, the one-pot method has the advantages that the time required for synthesizing nano particles with a multilayer core-shell structureis greatly saved. Through constructing a ''core-multi-shell'' structure, concentration quenching and luminescence color crosstalk are inhibited, and high-efficiency pure-color three-primary-color luminescence is realized. The nano crystal has a real-time color adjustment capability in full color gamut, and the adjustment method is simple and convenient.
Owner:HARBIN ENG UNIV

A simple method for preparing titanium dioxide multi-shell hollow spheres and sphere-in-sphere structures

The invention provides a simple method for preparing titanium dioxide multi-shell hollow spheres and a sphere-in-sphere structure. The method comprises the following steps: 1) adopting a dispersion polymerization method to prepare polystyrene used as seed spheres; 2) adopting a seed swelling polymerization method to prepare porous polystyrene-divinylbenzene high-polymer microspheres; 3) preparing titanium dioxide sol and a polymer/titanium dioxide composite: using isopropyl titanate, ethanol, deionized water and nitric acid to prepare the titanium dioxide sol, extracting the polymer microspheres prepared in the step 2) with toluene to be used as the polymer template and dispersing the polymer template in the titanium dioxide sol to prepare the polymer/titanium dioxide composite; and 4) putting the polymer/titanium dioxide composite in a muffle furnace which is preheated to 300-550 DEG C, and calcining to remove the polymer template and obtain the titanium dioxide multi-shell hollow spheres and sphere-in-sphere structure. The method provided by the invention is simple and practical and can be used to obtain the multi-shell hollow spheres and sphere-in-sphere structure. However, the traditional template-removing method can only obtain the porous titanium dioxide solid structure.
Owner:INST OF CHEM CHINESE ACAD OF SCI

Stannic oxide membrane electrode material for dye-sensitized solar cell and preparing method thereof

The invention provides a stannic oxide (SnO2) membrane electrode material for a dye-sensitized solar cell and a preparing method thereof. A carbon sphere synthesized through a hydrothermal method is utilized as a formwork, alkali treatment is carried out on the carbon sphere formwork to enhance the adsorbing capacity of the surface layer of the carbon sphere formwork to stannic ions, meanwhile the concentration of precursor tin salt solution is regulated to prepare the stannic oxide multi-shell hollow sphere with two adjacent outmost shells, and the hollow spheres are utilized as the dye-sensitized solar cell electrode materials to increase transmission paths of light in the membrane electrode. The stannic oxide membrane electrode material has excellent light scattering capacity, improves the absorption rate of dye molecules to light and obviously improves the photoelectric converting efficiency of the dye-sensitized solar cell. In addition, the preparing method has certain universality. The Zno, TiO2, Co3O4, CuO and Fe2O3 multi-shell hollow sphere with the two adjacent outmost shells is prepared by changing metal precursor salt solution. The preparing method is convenient to operate, high in controllability and wide in application prospect.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI
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