The present invention provides a high-hardness composite ceramic non-stick pan, comprising a pan base, a buffer layer and a zirconium-aluminum composite ceramic layer, wherein the buffer layer includes 20-30 parts by weight of titanium aluminide, 40-50 parts of strontium carbonate, 10-15 parts of calcium carbonate, 70-90 parts of bismuth oxide, 20-30 parts of graphene, 50-60 parts of neodymium oxide and 20-30 parts of barium carbonate; the zirconium-aluminum composite ceramic layer includes 50-60 parts by weight Zirconia, 20-30 parts alumina, 5-10 parts chromium oxide, 1-5 parts cerium oxide, 3-5 parts montmorillonite. In the high-hardness composite ceramic non-stick pan provided by the present invention, the buffer layer can have a good heat conduction effect, so that the temperature of the surface of the pan body is kept consistent, and the coating material obtained by the non-stick pan replaces the existing coating material. Teflon non-stick coating not only has good mechanical properties, but also wear-resistant, scratch-resistant, antibacterial, non-toxic and environmentally friendly.