The invention discloses high-yield-strength 600MPa-level ultra-thick hot-rolled H-shaped steel and a production method thereof, and belongs to the technical field of production of rolled steel. The hot-rolled H-shaped steel disclosed by the invention comprises the following elements in percentage by mass: 0.14 percent to 0.18 percent of C, 0.35 percent to 0.55 percent of Si, 1.10 percent to 1.40 percent of Mn, less than or equal to 0.020 percent of P, less than or equal to 0.015 percent of S, 0.080 percent to 0.12 percent of V, 0.020 percent to 0.040 percent of Nb, less than or equal to 0.025 percent of N, and the balance of Fe and inevitable impurities. The production process of the ultra-thick hot-rolled H-shaped steel comprises a step of pre-treatment of molten iron, a step of converter smelting, a step of argon blowing and refining, a step of LF refining, a step of full-protection and casting of shaped blank, a step of heating of blanks, a step of rolling the blanks, and performing QST (Quantitative Sensory Testing) cooling after rolling. According to the method disclosed by the invention, through reasonable proportioning of the ingredients and rolling process, particularly distribution of controlled reduction quantity and controlled-temperature rolling, the hot-rolled H-shaped steel with excellent comprehensive mechanical performance, the thickness 70mm to 100mm of flanges, the yield strength being more than or equal to 600MPa, the tensile strength being more than or equal to 750MPa, the elongation rate being more than or equal to 15 percent, 0-DEG C longitudinal V-shaped impact power KV2 mean value being more than or equal to 60J and Z-directional performance being more than or equal to 20 percent for high-rise buildings can be obtained.