The invention belongs to the field of nanometer semiconductor materials, and discloses a non-layered two-dimensional PbSe crystal material and a preparation method thereof. The preparation method comprises the following steps: (a) selecting a reaction container, marking the reaction container as an upstream region, a central region and a downstream region, selecting Se powder as a selenium source,and placing the Se powder in the upstream region; (b) selecting Pb3O4 as a lead source, mixing the Pb3O4 with potassium chloride so as to obtain a precursor, then placing the precursor in the centralregion, and selecting mica as a growth substrate to be placed in the downstream region; and (c) introducing argon into the reaction container as carrier gas, introducing hydrogen as reaction gas, andcarrying out a reaction under heating so as to obtain the non-layered two-dimensional PbSe crystal material on the mica substrate. The invention also discloses a product prepared by using the method.The method provided by the invention meets the preparation requirements of large-batch two-dimensional nanometer PbSe crystal materials; a product crystal has the advantages of smooth and clean surface, uniform morphology, uniform element distribution, rich and cheap raw materials, simple preparation, and convenience in popularization and large-scale production.