The invention discloses an additive of an orange leaf fertilizer and a preparation method thereof. The additive is prepared from, by weight, coal ash, rice straw, sodium selenite, pyroligneous liquor, blast furnace coal slag, sodium selenite, citric acid, ground phosphate rock, limestone, shells, kaolin, humic acid powder, glycine, aluminum sulfate, a 65-75% ethanol solution, plant additives and an appropriate amount of water. Natural rock flour contains a large amount of various elements and microelements, the addition of nutritive elements is particularly crucial for the leaf fertilizer, the concentration control amount is quite small due to the absorption limitation, and therefore the addition amount of microelements is more difficult to control. High-temperature pyrolysis is carried out on mineral stone, and then, a water solution rich in various complexing agents is utilized for extracting and chelating elements; on one hand, microelements can be successfully obtained; on the other hand, the chelated elements can be more easily absorbed.