The invention relates to a high-shielding UV treatment agent and a treatment process thereof. The high-shielding UV treatment agent is prepared from special modified acrylic ester, urethane acrylate,polyester acrylate, modified silicon dioxide, TMP3EOTA, HDDA, Ciba184, TPO, BASF819, leveling agents, butyl cellosolve, methylbenzene, isopropanol, ethyl acetate, butyl acetate and organic silicon leveling agents. A product obtained by using the formula and being treated by the treatment process has the advantages of high shielding performance, high wear performance, easy re-coating, high surfacedrying speed, high curing speed, fast film forming and the like; the problems of bottom hinging, color seepage and poor combination power do not occur after the re-coating; the treated coating surfacehas high smoothness, high luster degree, good smoothness and high qualified product rate, and solves the problems of nonuniform roughness degree, poor shielding performance, poor re-coating effect, construction inconvenience, low qualification product rate and the like of the surface coating of a product treated by the existing conventional UV treatment agent.