The invention discloses a measurement device for residual carbon quantity in fly ash. The device comprises a sampling unit, a measurement unit and a control unit, wherein the sampling unit is connected with an ash collecting device in the measurement unit through an ash collecting pipe; in the measurement unit, four crucibles are uniformly arranged on a rotating device along the circumference, the ash collecting device, a burning device and an ash discharge device are respectively arranged above the crucibles, a weighing device is arranged below the crucibles, an ejector rob is arranged on an elevating device, the ash collecting device, the ash discharge device, the rotating device, the elevating device and the weighing device are all connected with an electric device, and the burning device is connected with a temperature controller; and the measurement unit is connected with the control unit by the electric device. The invention has the advantages of excellent ash collection and discharge effect, high accuracy, no noise and no clamp phenomena.