The invention relates to the technical field of sensing films, in particular to a preparation method of a fluorescent dissolved
oxygen sensing film, which comprises the following steps: uniformly mixing a
diamine and dianhydride mixture with a polar
solvent in a protective gas
atmosphere, stirring at 25-80 DEG C to carry out
polymerization reaction for 0.5-2 hours to obtain a
polyamide acid solution, and continuously adding the polar
solvent to obtain the fluorescent dissolved
oxygen sensing film. The
viscosity of the
polyamide acid solution is adjusted to be 40-100 cP, the
mass percent of the mixture of the
diamine and the dianhydride is 5-20%, the
mass percent of the polar
solvent is 80-95%, the
molar ratio of the
diamine to the dianhydride in the mixture of the diamine and the dianhydride is 1: (0.8-1.5), and at least one of the diamine and the dianhydride contains
fluorine; adding a fluorescent indicator accounting for 0.01-5wt% of the
polyamic acid solution into the
polyamic acid solution, and uniformly mixing to obtain a
mixed solution;
coating the surface of a base material with the
mixed solution, and performing high-temperature curing in a protective gas
atmosphere; and naturally cooling the base material on which the fluorescent layer is formed to
room temperature to obtain the fluorescent dissolved
oxygen sensing film. The high
temperature resistance and air permeability of the sensing film are improved.