The invention discloses an environment-friendly heat-resistant waterborne polyurethane coating. The raw materials of the waterborne polyurethane coating comprise the following components in parts by weight: 50-80 parts of modified waterborne polyurethane, 10-30 parts of waterborne acrylic resin, 10-20 parts of epoxy resin, 5-8 parts of aliphatic polyisocyanate, 15-30 parts of organically modified clay, 8-20 parts of modified nano-cellulose, 5-20 parts of silk fibroin, 3-8 parts of nanometer titanium dioxide, 10-18 parts of nanometer montmorillonite, 5-8 parts of vegetable oil, 1-1.8 parts of glycerol, 0.5-1.8 parts of ethylene glycol propyl ether, 0.8-1.9 parts of propylene glycol monomethyl ether, 0-1.5 parts of pentaerythritol, 1-3 parts of organosilicone microspheres and 3-6 parts of modified carbon nanotubes. The environment-friendly heat-resistant waterborne polyurethane coating disclosed by the invention has the advantages of good heat resistance, strong water resistance, high hardness and long service life.