This invention discloses a core-shell material for the separation of
fluorine-containing electronic
specialty gases and its preparation method. Addressing the separation needs of
fluorine-containing electronic
specialty gases such as SF6 and CF4 commonly used in the
semiconductor and photovoltaic industries, this invention uses monodisperse PSD microspheres as the core and in-situ grows HKUST-1 under controlled low-temperature synthesis conditions to prepare a core-shell MOF
composite material. The
adsorption selectivity, separation performance, and mechanism of this material for
fluorine-containing gas /
nitrogen mixtures were investigated. The prepared PSD@HKUST-1 core-shell material exhibits a tunable pore structure and abundant adsorption sites, demonstrating excellent separation performance for fluorine-containing electronic
specialty gases, enabling efficient
recovery and purification of these gases. This invention features a simple process and novel structural design, showing promising application prospects in the fields of electronic chemical purification and
waste gas treatment.